Hostname: page-component-76fb5796d-zzh7m Total loading time: 0 Render date: 2024-04-30T00:21:36.881Z Has data issue: false hasContentIssue false

Field-Based Tests of Geochemical Modeling Codes: New Zealand Hydrothermal Systems

Published online by Cambridge University Press:  25 February 2011

Carol J. Bruton
Affiliation:
Lawrence Livermore National Laboratory, L-219, P.O. Box 808, Livermore, CA 94550
William E. Glassley
Affiliation:
Lawrence Livermore National Laboratory, L-219, P.O. Box 808, Livermore, CA 94550
William L. Bourcier
Affiliation:
Lawrence Livermore National Laboratory, L-219, P.O. Box 808, Livermore, CA 94550
Get access

Abstract

Hydrothermal systems in the Taupo Volcanic Zone, North Island, New Zealand are being used as field-based modeling exercises for the EQ3/6 geochemical modeling code package. Comparisons of the observed state and evolution of the hydrothermal systems with predictions of fluid-solid equilibria made using geochemical modeling codes will determine how the codes can be used to predict the chemical and mineralogical response of the environment to nuclear waste emplacement. Field-based exercises allow us to test the models on time scales unattainable in the laboratory.

Preliminary predictions of mineral assemblages in equilibrium with fluids sampled from wells in the Wairakei and Kawerau geothermal field suggest that affinity-temperature diagrams must be used in conjunction with EQ6 to minimize the effect of uncertainties in thermodynamic and kinetic data on code predictions.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Wolery, T.J., Lawrence Livermore National Laboratory Report UCRL-MA-110662 PT III (1992).Google Scholar
2 Wolery, T.J. and Daveler, S.A., Lawrence Livermore National Laboratory Report UCRL-MA-110662 PT IV (1992).Google Scholar
3 Simmons, S.F., Browne, P.R.L. and Brathwaite, R.L., Active and extinct hydrothermal systems of the North Island, New Zealand (Soc. Econ. Geol. Guidebook Vol. 15, Ft. Collins, CO, 1992).CrossRefGoogle Scholar
4 Buscheck, T.A. and Nitao, J.J., Proc. of Fourth Intl. High Level Radioactive Waste Mgmt. Conf. (1993), pp. 847867.Google Scholar
5 Glassley, W.E., Bruton, C.J. and Bourcier, W.L., in Scientific Basis for Nuclear Waste Management, this volume.Google Scholar
6 Bruton, C.J. and Viani, B.E., in Water-Rock Interaction 7, ed. by Kharaka, Y.K. and Maest, A.S. (A.A. Balkema, Netherlands, 1992), p. 705708.Google Scholar
7 Steiner, A., New Zealand Geological Survey Bull. 90 (1977).Google Scholar
8 Reyes, A.G., Giggenbach, W.F. and Christenson, B.W., Inst. of Geol. and Nuclear Sciences Proprietary Report 722305.15.15A (1993).Google Scholar
9 Christenson, B. W., Ph.D. thesis, Univ. of Auckland, New Zealand, 1987.Google Scholar
10 Henley, R.W., Truesdell, A.H. and Barton, P.B. Jr., Fluid-mineral equilibria in hydrothermal systems, Rev. in Econ. Geol. Vol. 1 (Soc. of Econ. Geol., Univ. of Texas, El Paso, Texas, 1984).CrossRefGoogle Scholar
11 Reed, M. and Spycher, N., Geochim. et Cosmochim. Acta 48 (1984).CrossRefGoogle Scholar
12 Helgeson, H.C., Delany, J.M., Nesbitt, H.W. and Bird, D.K., Am. Jour. Sci. 278–A (1978).Google Scholar