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Instantaneous Formation of Synroc-B Phases at Ambient Pressure

Published online by Cambridge University Press:  15 February 2011

J. M. Mchale  and
N. V. Coppa
J. M. Mchale
Affiliation:
Los Alamos National Laboratory, NMT-6, Mail Stop E5 10, Los Alamos, New Mexico 87545
N. V. Coppa
Affiliation:
Los Alamos National Laboratory, NMT-6, Mail Stop E5 10, Los Alamos, New Mexico 87545
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Abstract

The titanate based nuclear waste immobilization medium, Synroc-B, has been synthesized at atmospheric pressure from freeze dried nitrate precursors. Complete formation of the phase assemblage (CaTiO3, CaZrTi2O7, and BaAl2Ti5O14) occurred upon calcination of the nitrate precursor after only 10 minutes at 1100°C. This improvement in the preparation conditions may lead to practical application of the material in the safe disposal of high level nuclear waste and the immobilization of other strategic nuclear materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 412: Symposium V – Scientific Basis for Nuclear Waste Management XIX , 1995 , 297
Copyright
Copyright © Materials Research Society 1996

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References

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