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Interface Effect on Dipole-Dipole Interaction

Published online by Cambridge University Press:  15 February 2011

Michael Urbakh
Affiliation:
School of Chemistry, Tel-Aviv University, Tel Aviv 69978, Israel
Joseph Klafter
Affiliation:
School of Chemistry, Tel-Aviv University, Tel Aviv 69978, Israel
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Abstract

The nature of the pair interaction between dipoles embedded in a liquid in the vicinity of a non-metallic interface is investigated in the continuum limit. It is shown that the dipole-dipole interaction can be significantly modified in the presence of a boundary in liquids characterized by a nonlocal dielectric function or in liquids whose dielectric properties change due to geometrical restrictions. Different limits are studied and relationships to experimental observables are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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