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Kinetics of Phase Separation in Rigid Rod Polymer and Amorphous Polymer Mixtures

Published online by Cambridge University Press:  26 February 2011

Donald S. Nelson  and
David S. Soane
Donald S. Nelson
Affiliation:
University of California at Berkeley, Department of Chemical Engineering, Berkeley, CA 94720
David S. Soane
Affiliation:
University of California at Berkeley, Department of Chemical Engineering, Berkeley, CA 94720
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Abstract

Kinetics of phase separation of PBO in methane sulfonic acid are examined by time-resolved small angle light scattering. Thin films of polymer solutions are spincoated on microscope slides and observed in a controlled environment light scattering cell. These solutions appear to undergo spinodal decomposition, following Cahn- Hilliard type phase separation kinetics upon exposure to water, leading to an exponential increase in the scattered light intensity at short times.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 134: Symposium J – Materials Science and Engineering of Rigid-Rod Polymers , 1988 , 531
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

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