Hostname: page-component-76fb5796d-vvkck Total loading time: 0 Render date: 2024-04-27T02:14:47.144Z Has data issue: false hasContentIssue false

Mechanical Behaviour of Sputtered M-Fe-C (M = Cr, Mo, W) Carbides

Published online by Cambridge University Press:  10 February 2011

B. Trindade
Affiliation:
ICEMS, Departamento de Engenharia Mecânica da Faculdade de Ciências e Tecnologia, Universidade de Coimbra, 3030 Coimbra, Portugal
M. T. Vieira
Affiliation:
ICEMS, Departamento de Engenharia Mecânica da Faculdade de Ciências e Tecnologia, Universidade de Coimbra, 3030 Coimbra, Portugal
A. M. Amaro
Affiliation:
CEMUC, Departamento de Engenharia Mecânica da Faculdade de Ciências e Tecnologia, Universidade de Coimbra, 3030 Coimbra, Portugal
J. S. Cirne
Affiliation:
CEMUC, Departamento de Engenharia Mecânica da Faculdade de Ciências e Tecnologia, Universidade de Coimbra, 3030 Coimbra, Portugal
Get access

Abstract

Transition metal carbides of the VI Group of the Periodic Table (M-C where M = Cr, Mo, W) doped with iron were deposited as thin films on glass substrates by magnetron sputtering and were structurally and mechanically analysed by X-ray diffraction, laser interferometry and ultramicrohardness. The results show that the structures of the M-C binary systems depends on the position of the element M in the Periodic Table. Both W-C and Mo-C systems are crystalline (fcc structure) while the Cr-C is amorphous. The hardness and Young's modulus of the films increase from the carbides of the 1st to the 3rd long period. The addition of iron decreases the degree of structural order of the films as well as their Young's modulus. The films with higher hardness are those with a transition structure between crystalline and amorphous.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Trindade, B., Vieira, M. T. and Grosse, E. B., Acta Materialia, 46, 5 (1998) 1739.Google Scholar
[2] Gomes, J. F. S., Branco, F. B., Brito, F. M., Saraiva, J. G., Eusébio, M. L., Cime, J. S. and Cruz, A. C., in Recent Advances in Experimental Mechanics, edited by S. Gomes et al (Proc. of the 10th Int. Conf. On Experimental Mechanics, Lisbon, Portugal, 1994), p. 385.Google Scholar
[3] Doerner, M. F. and Nix, W. D., J. Mater. Res. 1 (4), (1986) 601.Google Scholar
[4] Trindade, A. C., Cavaleiro, A. and Fernandes, J. V., Journal of Testing and Evaluation (1994) 365.Google Scholar
[5] Gao, H., Chiu, C. H. and Lee, J., Int. J. Solids Structures 29, (1992) 2471.Google Scholar
[6] Davies, H. A., in Amorphous Metallic Alloys, edited by Luborsky, F. E. (Butterworths Monographs in Materials, 1983), p. 27.Google Scholar
[7] Mencik, J., Munz, D., Quandt, E. and Weppelmann, E. R., J. Mater. Res., 12, 9, (1997) 2475.Google Scholar