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Metal-Organic Precursors to high Temperature Superconductors Using 2-(2-Ethoxyethoxy)Ethanol

Published online by Cambridge University Press:  28 February 2011

Mary Rose Scozzafava ,
Wendell E. Rhine  and
Michael J. Cima
Mary Rose Scozzafava
Affiliation:
Ceramics Processing Research Laboratories, Massachusetts Institute of Technology, Cambridge, MA 02139
Wendell E. Rhine
Affiliation:
Ceramics Processing Research Laboratories, Massachusetts Institute of Technology, Cambridge, MA 02139
Michael J. Cima
Affiliation:
Ceramics Processing Research Laboratories, Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

The copper(II) alkoxide, bis(2-(2-ethoxyethoxy)ethoxide)copper(II), was prepared and had a solubility in organic solvents greatly exceeding those of simple copper(II) alkoxides (>0.4 mol/L in toluene at room temperature). Copper 2-(2-ethoxyethoxy)ethoxide (2-(2-ethoxyethoxy)ethoxide = 2,2-EEE) toluene or toluene/THF solutions gelled upon exposure to moisture. These solutions were hydrolysed with 0.2, 1.0, 2.0, 4.0, and 20.0 equivalents of H2O and the resulting powders were characterized by IR spectroscopy and SEM.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 169: Symposium M – High Temperature Superconductors: Fundamental Properties and Novel Materials Processing , 1989 , 393
Copyright
Copyright © Materials Research Society 1990

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References

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