Hostname: page-component-76fb5796d-qxdb6 Total loading time: 0 Render date: 2024-04-26T15:47:55.988Z Has data issue: false hasContentIssue false

Molecules with Polymerizable Ligands as Precursors to Porous Doped Materials

Published online by Cambridge University Press:  10 February 2011

L. G. Hubert-Pfalzgraf
Affiliation:
Université de Nice-Sophia-Antipolis, 06108 Nice Cédex (France)hubert@hermes.unice.fr
N. Pajot
Affiliation:
Université de Nice-Sophia-Antipolis, 06108 Nice Cédex (France)hubert@hermes.unice.fr
R. Papiernik
Affiliation:
Université de Nice-Sophia-Antipolis, 06108 Nice Cédex (France)hubert@hermes.unice.fr
S. Parraud
Affiliation:
CEA, Centre d'Etudes de Limeil-Valenton, 94195 Villeneuve-St-Georges Cddex (France)
Get access

Abstract

Titanium and aluminium alkoxide derivatives with polymerizable ligands such as 2- (methacryloyloxy)ethylacetoacetate (HAAEMA), oleic acid and geraniol (HOGE) have been obtained. The various compounds have been characterized by FT-IR and NMR 1H. Copolymerization with styrene and divinylbenzene affords porous doped organic materials which have been characterized by scanning electron microscopy (SEM), elemental analysis, density measurements.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Dagani, R., C&EN News, 33, (1995).Google Scholar
2. Liu, J.G. and Wilcox, D.L., Better Ceramics Through Chemistry VI (Mater. Res. Soc. Symp. Proc. 346, Pittsburgh, PA 1994), p. 201.Google Scholar
3. Even, W.R. and Gregory, D.P., MRS Bull, XIX, 14 (1994).Google Scholar
4. Kessler, V.G., Hubert-Plazgraf, L.G., Daniele, S., Gleizes, A., Chem. Mater, 6, 2336 (1994).Google Scholar
5. Mastrorilli, P. and Nobil, C.F., J. Mol. Cat, 94, 217 (1994).Google Scholar
6. Schubert, U., Huising, N., Lorenz, A., Chem.Mater, 7, 2010 (1995).Google Scholar
7. Pajot, N., Papiernik, R., Hubert-Pfalzgraf, L.G., Vaissermann, J. and Parraud, S., J. Chem. Soc., Chem. Commun, 1817 (1995).Google Scholar
8. Goel, S.C., Chiang, P.C., Gibbons, A.T. and Buhro, W.E., Better Ceramics Through Chemistry V(Mater. Res. Soc. Proc. 271, Pittsburgh, PA 1992), p. 3.Google Scholar
9. Hubert-Pfalzgraf, L.G., Decams, M., Daniele, S., Vaissermann, J., J.Sol-gel Technol., in press.Google Scholar
10. Cook, P, IIIOvertuff, G.E. and Haendler, B.L., S.A.Setts LLNL report (1992).Google Scholar