Hostname: page-component-848d4c4894-nr4z6 Total loading time: 0 Render date: 2024-05-22T10:19:04.430Z Has data issue: false hasContentIssue false

Organic-Inorganic Hybrid Dental Restorative Material

Published online by Cambridge University Press:  10 February 2011

Partha P. Paul
Affiliation:
Materials Engineering Department, Southwest Research Institute, San Antonio, Texas.
Scott F. Timmons
Affiliation:
Materials Engineering Department, Southwest Research Institute, San Antonio, Texas.
Walter J. Machowski
Affiliation:
Materials Engineering Department, Southwest Research Institute, San Antonio, Texas.
Get access

Abstract

A method for the preparation of dental restorative composites based on an organicinorganic hybrid material is presented. A sol-gel process was used to produce composites comprised of submicron silica in a polymer matrix. Using alcohols such as, 3-allyloxy-1, 2-propanediol and 2, 3-dihydroxypropyl methacrylate in combination with polysilicic acid or cyclic siloxane precursors, modified siloxanes are produced which can be polymerized photochemically with concurrent hydrolysis and condensation to generate a silica-reinforced polymer with superior mechanical properties and abrasion resistance.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Bowen, R. L., U.S. Patent 3 066 122 (1962).Google Scholar
2. Bowen, R. L., Marjenhoff, W. A., Adv. Dent. Res., 6, 4449 (1992).Google Scholar
3. Craig, R. G., J. Dent. Res., 58, 15441550 (1979).Google Scholar
4. Eick, J. D., Robinson, S. C., Byerley, M. J., Chappelow, C. C., Quintessence Int., 24, 632640 (1993).Google Scholar
5. Bouvier, D., Duprez, J. P., Nguyen, D., Lissac, M., Dent. Mater., 9, 365369 (1993).Google Scholar
6. Feilzer, A. J., de Gee, A. J., Davidson, C. L., J. Prosthet Dent., 59, 297300 (1988).Google Scholar
7. Byerley, T. J., Eick, J. D., Chen, G. P., Chappelow, C. C., Millich, F., Dent. Mater., 8,345350 (1992).Google Scholar
8. Strawberry, J. W., J. Dent. Res., 71, 14081412 (1992).Google Scholar
9. Sperling, L. H., Interpenetrating Polymer Network and Related Materials, (Plenum Press: New York, 1981).Google Scholar
10. Mark, J. E., CHEMTECH, 19, 230 (1989).Google Scholar
11. Ulrich, D. R., CHEMTECH, 18, 242 (1988).Google Scholar
12. Brinker, C. J., Scherer, G. W., Sol Gel Science, (Academic Press, New York, 1990).Google Scholar
13 Novak, B. M., Adv. Mater., 5, 422433 (1993).Google Scholar
14. Schmidt, H., J. Non-Cryst. Solids, 112, 419 (1989).Google Scholar
15. Ulrich, D. R., J. Non-Cryst. Solids, 121, 465 (1990).Google Scholar
16. Ellsworth, M. W., Novak, B. M., Chem. Mater., 5, 839844 (1993).Google Scholar
17. Goodwin, G. B., Kenney, M. E., Inorg. Chem., 29, 12161220 (1990).Google Scholar