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Pulsed Laser Annealing of Buried Damage in Ion Implanted Diamond

Published online by Cambridge University Press:  28 February 2011

Steven Prawer
Affiliation:
School of Physics, University of Melbourne, Parkville, Victoria, 3052, Australia.
D. N. Jamieson
Affiliation:
School of Physics, University of Melbourne, Parkville, Victoria, 3052, Australia.
S. P. Dooley
Affiliation:
School of Physics, University of Melbourne, Parkville, Victoria, 3052, Australia.
P. Spizzirri
Affiliation:
Department of Chemistry, University of Melbourne, Parkville, Victoria, 3052, Australia.
K. P. Ghiggino
Affiliation:
Department of Chemistry, University of Melbourne, Parkville, Victoria, 3052, Australia.
R. Kalish
Affiliation:
Solid State Instituteand Department of Physics, Technion-Israel Instituteof Technology, Haifa, 32000, Israel.
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Abstract

Damaged layers, buried underneath the surface of type IIa diamond slabs by 2.8 MeV C+ ion implantation have been subjected to irradiation with 14 ns pulses from a focused Nd-Glass laser. At high powers, ablation of the implanted surface was observed. However, the correct choice of laser power and wavelength results in annealing of the implanted layer without any disruption to the surface morphology. Annealing was confirmed by optical measurements showing a decrease in the GR-1 absorption band, and by channelled Rutherford Backscattering Spectroscopy on the small 10μm diameter laser irradiated spots. The results suggest that an undamaged diamond cap can be utilized to promote damage annealing of diamond by pulsed laser beams, for which the annealing in other materials has been shown to proceed via the melt. The surface cap is believed to aid in the production of extremely high internal pressures in the damaged layer during the laser pulse which prevents graphitization and promotes diamond regrowth.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

[1] Field, J.E., The Properties of Diamond, Academic Press, 1979 Google Scholar
[2] Braunstein, G. and Kalish, R., Nucl. Inst. Meth. 209/210, 387, (1983)Google Scholar
[3] Sandhu, G.S., Liu, B., Parikh, N.R., Hunn, J.D., Swanson, M.L., Wichert, Th., Deicher, M. and Skudlik, H., Mater. Res. Soc. Symp. Proc. Vol 162, 189, (1990)Google Scholar
[4] Sandhu, G.S., Swanson, M.L. and Chu, W.K., Appl. Phys. Lett, 55, 1397, (1989).Google Scholar
[5] Rothchild, M., Arnone, C. and Erlich, D.J., J. Vac. Sci. Technol. B, 4, 310, (1984)Google Scholar
[6] Gold, J.S., Bassett, W.A., Weathers, M.S. and Bird, J.M., Science, 225, 921, (1984)Google Scholar
[7] Prins, J.F., Derry, T.E. and Sellschop, J.P.F., Nucl. Inst. Meth. Phys. Res. B 18, 261, (1987)Google Scholar
[8] Venkatesan, T., Jacobson, D.C., Gibson, J.M., Elman, B.S., Braunstein, G., Dressel-haus, M.S., and Dresselhaus, G., Phys. Rev. Lett., 53, 360, (1984).Google Scholar
[9] Foti, G., Radiation Effects, 48, 161, (1980).Google Scholar
[10] Zeigler, J.F., Biersack, J.P and Littmark, U., The Stopping and Range of Ions in Solids (Pergamon, New York, 1985)Google Scholar
[11] The use of 1.4 MeV protons rather than the more usual 2.5 MeV He+ was necessitated by the inability of the latter to probe the full depth of the damage. The value of 1.4 MeV was chosen to maximize the channeling fraction for protons at a depth of 1.5 μm. This has the effect of increasing channeling contrast.Google Scholar
[12] Jamieson, D.N., Brown, R.A., Brown, C.G., and Williams, J.S., Nucl. Inst. Meth. B 54, 213, (1991).Google Scholar
[13] Walker, J., Rep. Prog. Phys. 42, 108, (1979).Google Scholar
[14] Dooley, S. and Jamieson, D.N., Nucl. Inst. Meth. Phys. Res. B., to be published.Google Scholar