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Rapidly Solidified Titanium

Published online by Cambridge University Press:  25 February 2011

F. H. Froes
Affiliation:
Air Force Wright Aeronautical Laboratories, Materials Laboratory, AFWAL/MLLS, Wright-Patterson AFB, OH 45433
R. G. Rowe
Affiliation:
General Electric Company, Corporate Research and Development Center, P.O. Box 8, Bldg. K-I, 263 MB, Schenectady, NY 12301
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Abstract

The attributes and requirements for rapid solidification (RS) are discussed and related to the characteristics of the titanium system. The extreme reactivity of liquid titanium requires the development of RS production methods tailored to this system. Compaction and processing techniques are presented followed by a discussion of the various alloy classes which have been produced by the RS approach: conventional alloys such as Ti-6Al-4V, rare earths, metalloids, eutectoid formers, beta alloys, amorphous materials, high aluminum alloys, aluminides, and other minor classes. Finally some thoughts on the future of this technology are presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 1986

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References

REFERENCES

1.German, R. M., Powder Metallurgy Science (MPIF, Princeton, NJ, 1984).Google Scholar
2.Froes, F. H. and Pickens, J. R., J. of Metals 36 (1), 1428 (1984).Google Scholar
3.Froes, F. H. and Eylon, D., in Titanium, Science and Technology, Vol. 1, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 267286.Google Scholar
4.Titanium Technology: Present Status and Future Trends, edited by Froes, F. H., Eylon, D., and Bomberger, H. B. (The Titanium Development Association, Dayton, OH, 1985).Google Scholar
5.Jones, H., Rapid Solidification of Metals and Alloys, Monograph No. 8, (Institution of Metallurgists, London, 1982).Google Scholar
6.Savage, S. J. and Froes, F. H., J. of Metals 36 (4), 2033 (1984).Google Scholar
7.Margolin, H. and Nielson, J. P., in Modern Materials, Advances in Development and Application, Vol. 2, edited by Hauser, H. H. (Academic Press, 1960), pp. 225325.Google Scholar
8.Molchanova, E. K., Phase Diagrams of Titanium Alloys, (Israel Program for Scientific Translations, Jerusalem, 1965).Google Scholar
9.Whang, S. H. and Chi, C. S., presented at the MRS Fall Meeting, Boston, MA, 1985 (and to be published).Google Scholar
10.Chi, C. S. and Whang, S. H. (private communication, 1985).Google Scholar
11.Whang, S. H. (private communication, 1985).Google Scholar
12.O'Neal, J. E., Sastry, S. M. L., Peng, T. C., and Tesson, J. F., Micro. Sci. 11, 143 (1983).Google Scholar
13.Whang, S. H., Lu, Y. Z., and Kim, Y-W., J. Mat. Sci. Letts. 4, 883 (1985).Google Scholar
14.Jackson, A. G., PhD thesis, University of Cincinnati, 1983.Google Scholar
15.Sastry, S. M. L., Meschter, P. J., and O'Neal, J. E., Met. Trans. A 15A, 1451 (1984).Google Scholar
16.Konitzer, D. G., Muddle, B. C., and Fraser, H. L., Met. Trans. A 14A, 1979 (1983).Google Scholar
17.Lu, Y. Z., Chi, C. S., and Whang, S. H., in Rapidly Quenched Metals, Vol. 1, edited by Steeb, S. and Warlimont, H. (Elsevier, Amsterdam, 1985), pp. 949952.Google Scholar
18.Whang, S. H., U.S. Patent No. 4 512 826 (23 April 1985).Google Scholar
19.Holcombe, C. E. and Serandos, T. R., Met. Trans. B 14B, 497 (1983).Google Scholar
20.Noesen, S. J., in International Transactions Vacuum Metallurgy Conference 1967, edited by Foster, E. L. (Am. Vac. Soc., New York, 1967), p. 503.Google Scholar
21.Broderick, T. F., Jackson, A. G., Jones, H., and Froes, F. H., Met. Trans. A, 16A, 1951 (1985).Google Scholar
22.Smith, C. H., General Electric Company (Schenectady, NY) Report No. 84CRD071, 1984.Google Scholar
23.Konitzer, D. G., Walters, K. W., Heiser, E. L., and Fraser, H. L., Met. Trans. B 15B, 149 (1984).Google Scholar
24.Peng, T. C., Sastry, S. M. L., and O'Neal, J. E., Met. Trans. A 16A, 1897 (1985).Google Scholar
25.Konitzer, D. G. and Fraser, H. L., Proceedings of the Powder Metallurgy Conference, Toronto, Ontario, Canada, 1984 (to be published).Google Scholar
26.Anoshkin, N. F. (private communication, 1980).Google Scholar
27.Sastry, S. M. L., Peng, T. C., Meschter, P. J., and O'Neal, J. E., J. of Metals 35 (9), 2128 (1983).Google Scholar
28.Yolton, C. F. and Moll, J. H., U.S. Patent No. 4 544 404 (1 October 1985).Google Scholar
29.Yolton, C. F. and Moll, J. H., presented at the First International ASM Conference on Rapidly Solidified Materials, San Diego, CA, 1986 (and to be published).Google Scholar
30.Rowe, R. G., Broderick, T. F., Koch, E. F., and Froes, F. H., presented at the First International ASM Conference on Rapidly Solidified Materials, San Diego, CA, 1986 (and to be published).Google Scholar
31.Gigliotti, M. F. X., Rowe, R. G., Wasielewski, G. E., Scarr, G. K., and Williams, J. C., presented at the MRS Fall Meeting, Boston, MA, 1985 (and to be published).Google Scholar
32.Rowe, R. G. and Koch, E. F., presented at the First International ASM Conference on Rapidly Solidified Materials, San Diego, CA, 1986 (and to be published).Google Scholar
33.Ray, R., U.S. Patent No. 4 471 831 (18 September 1984).Google Scholar
34.Whang, S. H., Chi, C. S., and Lu, Y. Z., in Rapidly Quenched Metals, Vol. 1, edited by Steeb, S. and Warlimont, D. (Elsevier, Amsterdam, 1985), pp. 115118.Google Scholar
35.Pond, R. B. and Winter, J. M., Mat. Sci. Engr. 23, 87 (1976).Google Scholar
36.Peng, T. C., Sastry, S. M. L., O'Neal, J. E., and Tesson, J. F., in Lasers in Materials Processing, edited by Metzbower, E. A. (ASM, Metals Park, OH, 1983), p. 241.Google Scholar
37.Hayes, F. H., Bomberger, H. B., Froes, F. H., Kaufman, L., and Burte, H. M., J. of Metals 36 (6), 7076 (1984).Google Scholar
38.Raybould, D., in Progress in Powder Metallurgy 1982, Vol. 38, edited by Bewley, J. G. and McGee, S. W. (MPIF, Princeton, NJ, 1983), pp. 575592.Google Scholar
39.Roman, O. V. and Gorobtsov, V. G., in Shock Waves and High-Strain-Pate Phenomena in Metals, edited by Meyers, M. A. and Murr, L. E. (Plenum Press, New York, 1980).Google Scholar
40.Linse, V. D., in Sagamore Army Materials Research Conference Proceedings, edited by Bruggeman, Gordon and Weiss, Volker (1983), pp. 381404.Google Scholar
41.Roman, O. V., Boiko, Y. V., Gorobtsov, V. G., and Shelegov, V. I., in Titanium, Science and Technology, Vol. 1, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 333337.Google Scholar
42.Kolachev, B. A. and Nosov, V. K., in Titanium, Science and Technology, Vol. 1, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 625631.Google Scholar
43.Teal, K. R., Jackson, A. G., and Froes, F. H. (work in progress, 1984-1986).Google Scholar
44.Gigliotti, M. F. X. (private communication, 1985).Google Scholar
45.Broderick, T. F., Froes, F. H., and Jackson, A. G., in Rapidly Solidified Metastable Materials, Vol. 28, edited by Kear, B. H. and Giessen, B. C. (Elsevier Science Publishers, New York, 1984), p. 345.Google Scholar
46.Boswell, P. C. and Chadwick, G. A., Scripta Met., 2, 459 (1977).Google Scholar
47.Belov, A. F. and Polkin, I. S., “Modern Trends in Titanium Production and Processing,” Germany Metallurgical Society Workshop, University of Nuremberg, Erlangen, July 1982.Google Scholar
48.Peng, T. C., Sastry, S. M. L., and O'Neal, J. E., in Lasers in Metallurgy, edited by Mukherjee, K. and Mazumder, J. (TMS Publications, New York, 1981), pp. 279292.Google Scholar
49.O'Neal, J. E., Peng, T. C., and Sastry, S. M. L., in Proceedings of 39th Annual EMSA Meeting, edited by Bailey, G. W. (Claitor's Publishing Division, Baton Rouge, LA, 1981), pp. 6667.Google Scholar
50.Muddle, B. C., Konitzer, D. G., and Fraser, H. L., in Strength of Metals and Alloys, Vol. 1, edited by Gifkins, R. C. (Pergamon Press, Oxford, 1983), pp. 313318.Google Scholar
51.Wright, I. G. and Wilcox, B. A., Battelle Columbus Laboratories Report No. AD-781-133, 1974.Google Scholar
52.Snow, D. B., in Laser Processing of Materials, edited by Mukherjee, K. and Mazumder, J. (TMS Publications, Warrendale, PA, 1984), pp. 8398.Google Scholar
53.Konitzer, D. G., Muddle, B. C., Kirchheim, R., and Fraser, H. L., in Rapidly Quenched Metals, Vol. 1, edited by Steeb, S. and Warlimont, H. (Elsevier, Amsterdam, 1985) pp. 953956.Google Scholar
54.Konitzer, D. G., Muddle, B. C., and Fraser, H. L., Scripta Met. 17, 963 (1983).Google Scholar
55.Konitzer, D. G., Muddle, B. C., Fraser, H. L., and Kirchheim, R., in Titanium, Science and Technology, Vol. 1, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 405410.Google Scholar
56.Konitzer, D. G. (private communication, 1985).Google Scholar
57.Whang, S. H., J. of Metals 36 (4), 3440 (1984).Google Scholar
58.Fraser, H. L. (private communication, 1985).Google Scholar
59.Whang, S. H., “RS Titanium Alloys for High Temperature Applications,” (to be published in J. Mat. Sci.).Google Scholar
60.Rowe, R. G., Sutliff, J. A., and Koch, E. F., presented at the 1985 MRS Fall Meeting, Boston, MA, 1985 (and to be published).Google Scholar
61.Sutliff, J. A. and Rowe, R. G., presented at the 1985 MRS Fall Meeting, Boston, MA, 1985 (and to be published).Google Scholar
62.Brown, L. M. and Ham, R. K., in Strengthening Methods in Crystals, edited by Kelly, A. and Nicholson, R. B. (Elsevier, New York, 1971), p. 9.Google Scholar
63.Sastry, S. M. L., Peng, T. C., and Beckerman, L. P., Met. Trans. A 15A, 1465 (1984).Google Scholar
64.Vogt, R. G., Eylon, D., and Froes, F. H. (work in progress, 1983-1986).Google Scholar
65.Sastry, S. M. L., Peng, T. C., Meschter, P. J., and O'Neal, J. E., J. of Metals 35 (9), 2128 (1983).Google Scholar
66.Sastry, S. M. L., Peng, T. C., and O'Neal, J. E., in Titanium, Science and Technology, Vol. 1, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 397404.Google Scholar
67.Jackson, A. G. and Froes, F. H., in Titanium, Science and Technology, Vol. I, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 381387.Google Scholar
68.Chi, C. S. and Whang, S. H., in Rapidly Solidified Metastable Materials, Vol. 28, edited by Kear, B. H. and Giessen, B. C. (Elsevier Science Publishers, New York, 1984), pp. 353360.Google Scholar
69.Frausto, P. R., Jackson, A. G., Clauer, A. H., and McCall, J. L., in Microstructural Science, Vol. 10, edited by Richardson, White, and McCall, (Elsevier Science Publishers, New York, 1982), pp. 103112.Google Scholar
70.Whang, S. H., Lu, Y. Z., and Giessen, B. C., in Rapidly Solidified Metastable Materials, Vol. 28, edited by Kear, B. H. and Giessen, B. C. (Elsevier Science Publishers, New York, 1984), pp. 367373.Google Scholar
71.Franti, G. W., Williams, J. C., and Aaronson, H. I., Met. Trans. A 9A (11), 1641 (1978).Google Scholar
72.Bomberger, H. B. and Froes, F. H., AFWAL Report No. TR-84-4164, 1985.Google Scholar
73.Gross, J., Mallory-Sharon Titanium Corporation Internal Report No. 1000R164, 1956.Google Scholar
74.Farrar, P. A. and Margolin, H., Army Materials and Mechanics Research Center Report No. WAL TR 401/303-13, 1967.Google Scholar
75.Hunter, D. B., AFWAL Report TR-405/2-15, Part II, 1966.Google Scholar
76.Krishnamurthy, S., Vogt, R. G., Eylon, D., and Froes, F. H., in Progress in Powder Metallurgy, Vol. 39, edited by Nayar, H. S., Kaufman, S. M., and Meiners, K. E. (MPIF, Princeton, NJ, 1984), pp. 603623.Google Scholar
77.Collings, E. W., Maringer, R. E., and Mobley, C. E., AFMIL Report No. TR-78-70, 1978.Google Scholar
78.Sastry, S. M. L., Peng, T. C., and O'Neal, J. E., presented at the 1984 MPIF/APMI International PM Conference, Toronto, Ontario, Canada (to be published).Google Scholar
79.Peng, T. C., Sastry, S. M. L., and O'Neal, J. E., in Rapid Solidification Technology III, edited by Mehrabian, R. (NBS, Gaithersburg, MD, 1982), pp. 452457.Google Scholar
80.Baeslack, W. A. III, Krishnamurthy, S., and Froes, F. H., in Strength of Metals and Alloys, Vol. 2, edited by McQueen, H. J., Bailon, J-P., Dickson, J. I., Jonas, J. J., and Akben, M. G. (Pergamon Press, Oxford, 1985), pp. 16331638.Google Scholar
81.Krishnamurthy, S., Jackson, A. G., Jones, H., and Froes, F. H., “BetaEutectoid Decomposition in Rapidly Solidified Titanium-Nickel Alloys,” (submitted to Met. Trans., 1984).Google Scholar
82.Krishnamurthy, S., Jackson, A. G., Eylon, D., Boyer, R. R., and Froes, F. H., in Rapidly Quenched Metals, Vol. 1, edited by Steeb, S. and Warlimont, H. (Elsevier Science Publishers, Amsterdam, 1985), pp. 945948.Google Scholar
83.Krishnamurthy, S., Weiss, I., Eylon, D., and Froes, F. H., in Strength of Metals and Alloys, Vol. 2, edited by McQueen, H. J., Bailon, J-P., Dickson, J. I., Jonas, J. J., and Akben, M. G. (Pergamon Press, Oxford, 1985), pp. 16271632.Google Scholar
84.Baeslack, W. A. III, Weeter, L., Krishnamurthy, S., Smith, P. R., and Froes, F. H., in Rapidly Solidified Metastable Materials, Vol. 28, edited by Kear, B. H. and Giessen, B. C. (Elsevier Science Publishers, NY, 1984), pp. 375379.Google Scholar
85.Krishnamurthy, S., Vogt, R. G., Eylon, D., and Froes, F. H., in Rapidly Solidified Metastable Materials, Vol. 28, edited by Kear, B. H. and Giessen, B. C. (Elsevier Science Publishers, NY, 1984), pp. 361366.Google Scholar
86.Baeslack, W. A. III, Krishnamurthy, S., and Froes, F. H., “A Study of Rapidly-Quenched Microstructures in a Hypereutectoid Ti40 wt%W Alloy,” (accepted for publication in J. of Material Science, 1985).Google Scholar
87.Krishnamurthy, S., Jackson, A. G., Weiss, I., and Froes, F. H., “Aging Response of Rapidly Solidified Titanium-Tungsten Alloys with Nickel and Silicon Additions,” presented at the First International ASM Conference on Rapidly Solidified Materials, San Diego, CA, February 1986 (and to be published).Google Scholar
88.Krishnamurthy, S., Eylon, D., Weiss, I., and Froes, F. H., “Age Hardening Behavior of a Rapidly Solidified Ti-15Cr-4A1 Alloy,” presented at the TMS-AIME Conference on Mechanical Behavior of RS Material, New York City, February 1985 (and to be published).Google Scholar
89.Krishnamurthy, S. and Froes, F. H. (work in progress, 1985).Google Scholar
90.Vogt, R. G., Smith, P. R., Eylon, D., and Froes, F. H. (work in progress, 1983-1986).Google Scholar
91.Broderick, T. F., Froes, F. H., and Snide, J. A. (work in progress, 1985-1986).Google Scholar
92.Broderick, T. F. and Froes, F. H. (work in progress, 1984-1986).Google Scholar
93.Froes, F. H. and Smith, P. R. (unpublished work, 1985).Google Scholar
94.Gutierrez, M., Martorell, I. A., and Froes, F. H. (work in progress, 1986).Google Scholar
95.Polk, D. E. and Giessen, B. C., Metallic Glasses, (ASM, Metals Park, OH, 1978), pp. 135.Google Scholar
96.Carbonara, R. S., Gaspar, T. A., Raman, R. V., Maringer, R. E., and McCall, J. L., MCIC Report No. 81–45, 1981.Google Scholar
97.Kovneristy, Yu. K., Osipov, E. K., Trofimova, E. A., Baikov, A. A., Tomashov, N. D., and Skvortsova, I. B., in Titanium, Science and Technology, Vol. 1, edited by Lutjering, G., Zwicker, U., and Bunk, W. (DGM, Oberursel, West Germany, 1985), pp. 203208.Google Scholar
98.Tanner, L. E. and Ray, R., Scripta Met. 11, 783 (1977).Google Scholar
99.Tanner, L. E., Scripta Met. 12, 703 (1978).Google Scholar
100.Tanner, L. E. and Ray, Ranjan, Scripta Met. 14, 657 (1980).Google Scholar
101.Tanner, L. E. and Ray, R., Acta Met. 27, 1727 (1979).Google Scholar
102.Inoue, A. et al., in Proceedings of the Industrial Conference on Titanium, (1980), pp. 19361944.Google Scholar
103.Whang, S. H. and Lu, Y. Z., in Proceedings of RSP, Principles and Technologies, III, edited by Mehrabian, R. (NBS, Gaithersburg, MD, 1983), pp. 286290.Google Scholar
104.Whang, S. H., Mat. Sci. Eng. 57, 87 (1983).Google Scholar
105.Whang, S. H., J. Non-Cryst. Sol. 61 and 62, 841 (1984).Google Scholar
106.Whang, S. H., Scripta Met. 18, 309 (1984).Google Scholar
107.Inoue, A., Kimura, H., Sakai, S., and Masumoto, T., in Titanium ‘80, Science and Technology, Vol. 2, edited by Kimura, H. and Izumi, O. (TMS Publications, Warrendale, PA, 1980), pp. 11371145.Google Scholar
108.Suryanarayana, C., Inoue, A., and Masumoto, T., in Titanium ‘80, Science and Technology, Vol. 1, edited by Kimura, H. and Izumi, O. (TMS Publications, Warrendale, PA, 1980), pp. 699707.Google Scholar
109.Gao, Y. Q. and Whang, S. H., J. Non-Cryst. Sol. 70, 85 (1985).Google Scholar
110.Martin, P. L., Mendiratta, M. G., and Lipsitt, H. A., Met. Trans. A 14A, 2170 (1983).Google Scholar
111.Konitzer, D. G. and Fraser, H. L., presented at the 1984 MRS Fall Meeting, Boston, MA, 1984 (and to be published).Google Scholar
112.Bomberger, H. B. and Froes, F. H. (work in progress, 1983-1986).Google Scholar
113.Yolton, C. F., Smith, P. R., Bomberger, H. B., and Froes, F. H. (work in progress, 1985-1986).Google Scholar
114.Sastry, S. M. L. (work in progress, 1985-1986).Google Scholar
115.Mahajan, Y. R., Froes, F. H., H. B. Bomberger (work in progress, 1984-1986).Google Scholar
116.Dekock, C., Froes, F. H., and Vogt, R. G. (work in progress, 1985).Google Scholar