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Sequence-Controlled Vinyl Polymers by Transition Metal-Catalyzed Step-Growth and Living Radical Polymerizations

Published online by Cambridge University Press:  06 February 2014

Kotaro Satoh  and
Masami Kamigaito
Kotaro Satoh
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, 464-8603, Japan
Masami Kamigaito
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, 464-8603, Japan
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Abstract

The metal-catalyzed step-growth radical polymerization was achieved to enable two systems for preparing tailored polymeric structures, i.e., sequence-regulated vinyl copolymer and periodically-functionalized polymer. The former is a novel strategy for preparing sequence-regulated vinyl copolymers by step-polymerization of sequence-regulated vinyl oligomers prepared from common vinyl monomers as building blocks. The later deals the simultaneous chain- and step-growth radical polymerization, which resulted in the polymers with periodic functional groups.

Keywords

polymerpolymerizationchemical synthesis
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1613: Symposium 4D – New Trends in Polymer Chemistry and Characterization-2013 , 2014 , pp. 17 - 21
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Kharasch, M. S., Jensen, E. V., Urry, W. H., Science 102, 128 (1945).Google Scholar
Kato, M., Kamigaito, M., Sawamoto, M., Higashimura, T., Macromolecules 28, 1721 (1995).CrossRefGoogle Scholar
Wang, J.-S., Matyjaszewski, K., J. Am. Chem. Soc. 117, 5614 (1995).CrossRefGoogle Scholar
Satoh, K., Kamigaito, M., Sawamoto, M., “Transition Metal Complexes for Metal-Catalyzed Atom Transfer Controlled/Living Radical Polymerization,” Polymer Science: A Comprehensive Reference, ed. Matyjaszewski, K. Moeller, M. (Elsevier, 2012) Amsterdam, Netherlands,vol. 3, pp. 429–461 (2012).CrossRefGoogle Scholar
Satoh, K., Mizutani, M., Kamigaito, M., Chem. Commun. 12, 1260 (2007).CrossRefGoogle Scholar
Satoh, K., Ozawa, S., Mizutani, M., Nagai, K., Kamigaito, M., Nat. Commun., 1: 6, doi: 10.1038/ncomms1004 (2010).CrossRefGoogle Scholar
Satoh, K., Abe, T., Kamigaito, M., ACS. Symp. Ser. 1100, 133 (2012).Google Scholar
Mizutani, M., Satoh, K., Kamigaito, M., J. Am. Chem. Soc. 132, 7498 (2010).CrossRefGoogle Scholar
Mizutani, M., Satoh, K., Kamigaito, M., Macromolecules 4, 2382 (2011).CrossRefGoogle Scholar