Hostname: page-component-848d4c4894-m9kch Total loading time: 0 Render date: 2024-06-07T21:58:05.890Z Has data issue: false hasContentIssue false
  • English
  • Français

Slowing Down of Molecular Reorientations in [Ni(NH3)6](N03)2

Published online by Cambridge University Press:  22 February 2011

Jerzy A. Janik ,
Jacek Mayer ,
Jan Krawczyk ,
Tormod Riste ,
Kaare Otnes ,
Janina M. Janik  and
Teresa Stanek
Jerzy A. Janik
Affiliation:
H.Niewodniczański Institute of Nuclear Physics, Kraków, Poland
Jacek Mayer
Affiliation:
H.Niewodniczański Institute of Nuclear Physics, Kraków, Poland
Jan Krawczyk
Affiliation:
H.Niewodniczański Institute of Nuclear Physics, Kraków, Poland
Tormod Riste
Affiliation:
Institutt for energiteknikk, Kjeller, Norway
Kaare Otnes
Affiliation:
Institutt for energiteknikk, Kjeller, Norway
Janina M. Janik
Affiliation:
Jagiellonian University, Faculty of Chemistry, Kraków, Poland.
Teresa Stanek
Affiliation:
Jagiellonian University, Faculty of Chemistry, Kraków, Poland.
Get access

Abstract

Quasielastic neutron scattering measurements of [Ni(NH3)6](N03)2 were made with two different resolutions of ca. 140 and 30 μeV. The following suggestions are analyzed:

1. The NH3 rotational diffusion model is more adequate than NH3 120° jump model.

2. Some NH3 groups slow down whereas some rotate rapidly.

3. There exists an additional QNS component close to the phase II/phase III transition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 376: Symposium BB – Neutron Scattering in Materials Science , 1994 , 769
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

References:

1 Janik, J.M. Janik, Migdal-Mikuli, A., Mikuli, E., Otnes, K.; Physica 11OB, 62 (1981).Google Scholar
2 Belushkin, , Janik, J.A., Janik, J.M., Natkaniec, I., Nawrocik, W., Olejarczyk, W., Otnes, K., Zaleski, T.; Physica 122B, 217 (1983).Google Scholar
3 Migdal-Mikuli, , Mikuli, E., Rachwalska, M., Stanek, T., Janik, J.M., Janik, J.A.; Physica 104B, 331 (1981).Google Scholar
4 Andresen, A., Fjellvaag, H., Janik, J.A., Mayer, J., Ściesiński, J., Janik, J.M., Migdal-Mikuli, A., Mikuli, E., Rachwalska, M., Stanek, T.; Physica 138B , 295 (1986).Google Scholar
5 Janik, J.M., Janik, J.A., Pick, R.M., Le Postollec, M.; J. Raman Spectr. 18, 493 (1987).Google Scholar