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Stoichiometric Determination of Graphite Intercalation Compounds Using Rutherford Backscatiering Spectrometry

Published online by Cambridge University Press:  25 February 2011

L. Salamanca-Riba ,
B.S. Elman ,
M.S. Dresselhaus  and
T. Venkatesan
L. Salamanca-Riba
Affiliation:
Department of Physics;
B.S. Elman
Affiliation:
Department of Physics;
M.S. Dresselhaus
Affiliation:
Department of Physics; Department of Electrical Engineering and Computer Science; Center for Materials Science and Engineering;Massachusetts Institute of Technology, Cambridge, MA 02139, USA
T. Venkatesan
Affiliation:
Bell Laboratories, Murray Hill, NJ 07974, USA
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Abstract

Rutherford backscattering spectrometry (RBS) is used to characterize the stoichiometry of graphite intercalation compounds (GIC). Specific application is made to several stages of different donor and acceptor compounds and to commensurate and incommensurate intercalants. A deviation from the theoretical stoichiometry is measured for most of the compounds using this non-destructive method. Within experimental error, the RBS results agree with those obtained from analysis of the (00ℓ) x-ray diffractograms and weight uptake measurements on the same samples.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 27: Symposium E – Ion Implantation and Ion Beam Processing of Materials , 1983 , 481
Copyright
Copyright © Materials Research Society 1984

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References

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