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Structure Characterization and Electrochemical Characteristics of Carbon Nanotube- Spinel Li4Ti5O12 Nanoparticles

  • Xiangcheng Sun (a1), A. Iqbal (a2), I. D. Hosein (a3), M. J. Yacaman (a4), Z. Y. Tang (a5), P. V. Radovanovic (a3) and B. Cui (a1)...

Carbon nanotube-spinel lithium titanate (CNT-Li4Ti5O12) nanoparticles have been synthesized by hydrothermal reaction and higher-temperature calcinations with LiOH·H2O and TiO2 precursors in the presence of carbon nanotubes sources. The CNT-Li4Ti5O12 nanoparticles have been characterized by X-ray diffraction (XRD), high angle annular dark field (HAADF) images, and selected area electron diffraction (SAED). The particles exhibited a spinel cubic crystal phase and homogenous size distribution, with sizes around 50-70 nm. HAADF imaging confirmed that carbon content exists on the surface of the CNT-Li4Ti5O12 nanoparticles with graphitic carbon coating of 3-5 nm thickness under 800oC in the Ar gas. The graphitic carbon phase was further confirmed with Raman spectroscopy analysis on powder samples. Electrochemical characteristics were evaluated with galvanostatic discharge/charge tests, which showed that the initial discharge capacity is 172 mA·h/g at 0.1C. The nanoscale carbon layers uniformly coated the particles, and the interconnected carbon nanotube network is responsible for the improved charge rate capability and conductivity.

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1. Ohzuku, T., Ueda, A., and Yamamoto, N., J. Electrochem. Soc. 142, 1431 (1995)
2. Zaghib, K., Armand, M., and Gauthier, M., J. Electrochem. Soc. 145, 3135 (1998)
3. Nakahara, K., Nakajima, R., Matsushima, T., Majima, H., J. Power Sources, 117, 131 (2003)
4. Zaghib, K., Simoneau, M., and Armand, M., J. Power Sources, 8182, 300 (1999)
5. Chen, C. H., Vaughey, J. T., Jansen, A. N., Dees, D. W., Kahaian, A. J., Goacher, T., and Thackeray, M. M., J. Electrochem. Soc. 148, A102 (2001)
6. Cheng, L., Liu, H. J., Zhang, J. J., Xiong, H. M. and Xia, Y. Y., J. Electrochem. Soc. 153, A1472 (2006)
7. Jiang, C. H., Ichihara, M., Honma, I., and Zhou, H. S., Electrochim. Acta, 52, 6470 (2007)
8. Li, J. R., Tang, Z. L., and Zhang, Z. T., Electrochem. Commun. 7, 894 (2005)
9. Huang, S., Woodson, M., Smalley, R., and Liu, J., Nano Lett. 4, 1025 (2004)
10. Liu, H., Feng, Y., Wang, K., and Xie, J., J. Phys. Chem. Solids, 69, 2037 (2008)
11. Wang, Y., Liu, H., Wang, K., Eiji, H., Wang, Y. and Zhou, H., J. Mater. Chem. 19, 6789 (2009)
12. Al-Muhtaseb, S. A., and Ritter, J. A., Adv. Mater. 15, 101(2003)
13. Lu, H. W., Zeng, W., Li, Y. S., and Fu, Z. W., J. Power Sources, 164, 874 (2007)
14. Kim, J. Y., and Cho, J. P., Electrochem. Solid-State Lett. 10, A81(2007)
15. Prakash, A. S., Manikandan, P., Ramesha, K., Sathiya, M., Tarascon, J. M., and Shukla, A. K., Chem. Mater. 22, 2857(2010)
16. Sorensen, E. M., Barry, S. J., Jung, H. K., Rondinelli, J. R., Vaughey, J. T. and Poeppelmeier, K. R., Chem. Mater. 18, 482 (2006)
17. Zhu, G.N., Liu, H.J., Zhuang, J. H., Wang, C.X., Wang, Y.G., and Xia, Y.Y., Energy Environ. Sci. 4, 4016 (2011)
18. Cheng, L., Yan, J., Zhu, G. N., Luo, J. Y., Wang, C. X., and Xia, Y. Y., J. Mater. Chem. 20, 595(2010)
19. Gao, J., Ying, J. R., Jiang, C. Y., and Wan, C. R., J. Power Sources, 166, 255 (2007)
20. Huang, J. J. and Jiang, Z. Y., Electrochim. Acta, 53, 7756 (2008)
21. Park, K.S., Benayad, A., Kang, D.J., and Doo, S.G., J. Am. Chem. Soc. 130, 14930 (2008)
22. Kim, H. K., Bak, S. M., and Kim, K. B., Electrochem. Communication 12, 1768 (2010)
23. Li, B. H., Ning, F., He, Y. B., Du, H. D., Yang, Q.H., Ma, J., Kang, F.Y., and Hsu, C.T., Int. J. Electrochem. Sci., 6, 3210 (2011)
24. Amine, K., Belharouak, I., Chen, Z. H., Tran, T., Yumoto, H., Ota, N., Myung, S. T. and Sun, Y. K., Adv. Mater. 22, 3052 (2010)
25. Li, X., Qu, M. Z., Huai, Y.J., and Yua, Z.L., Electrochimica Acta, 55, 2978 (2010)
26. Cheng, L., Yan, J., Zhu, G. N., Luo, J.Y., Wang, C. X., and Xia, Y.Y., J. Mater. Chem. 20, 595 (2010)
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