Hostname: page-component-848d4c4894-ndmmz Total loading time: 0 Render date: 2024-05-22T05:51:22.380Z Has data issue: false hasContentIssue false
  • English
  • Français

Vanadium-Oxo Based Hybrid Organic-Inorganic Copolymers

Published online by Cambridge University Press:  10 February 2011

A. Campero ,
A. M. Soto ,
J. Maquet  and
C. Sanchez
A. Campero
Affiliation:
Departamento de Química, Universidad Autónoma Metropolitana (Iztapalapa), México DF 09340, México, acc35@xanum.uam.mx
A. M. Soto
Affiliation:
Departamento de Química, Universidad Autónoma Metropolitana (Iztapalapa), México DF 09340, México, acc35@xanum.uam.mx
J. Maquet
Affiliation:
Laboratoire de Chimie de la Matière Condensé-URA 1466, Université Pierre et Marie Curie, 4, place Jussieu, Paris, France
C. Sanchez
Affiliation:
Laboratoire de Chimie de la Matière Condensé-URA 1466, Université Pierre et Marie Curie, 4, place Jussieu, Paris, France
Get access

Abstract

We describe the synthesis and characterization of hybrid organicinorganic copolymer materials formed by the reaction of the transition metal alkoxide VO(OAmt)3 with the chelating monomer ligand acetoacetoxyethylmethacrylate (AAEM). By the simultaneous induction of the organic and inorganic polymerization reactions, covalent bonds are formed between both types of interpenetrating components. The organic chelating moiety of AAEM is linked through its ß-diketo function to the vanadium-oxo species.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 527
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Livage, J., Henry, M. and Sanchez, C., Progress in Solid State Chemistry, 18,259 (1988).Google Scholar
2. Brinker, C. J., and Scherrer, G., Sol-Gel Chemistry. the Physics and Chemistry of Sol-Gel Processing, Academic Press, San Diego, 1989.Google Scholar
3. Chandler, C.D., Roger, C., and Hampden-Smith, M., Chem. Rev. 93, 1205 (1993).Google Scholar
4. Avnir, D., Levy, D. and Reisfeld, R., J. Phys. Chem. 88, 5956 (1984).Google Scholar
5. Schmidt, H. and Seiferling, B., (Mat. Res. Soc. Proc. 73,1986), p.7 3 9.Google Scholar
6. Novak, B.M., Adv. Mater. 5, 422 (1993).Google Scholar
7. Coltrain, B.K., Landry, C.J.T.,, O'Reilly, J.M., Chamberlain, A.M., Rakes, G.A., Sedita, J.S.S., Kelts, L.W., Landry, M.R. and Long, V.K., Chem. Mater. 5, 1445 (1993).Google Scholar
8. Sanchez, C. and Ribot, F., New Journal Chemistry 18, 1007 (1994).Google Scholar
9. Sanchez, C. and In, M., J. Non-Cryst. Solids 147&148, 1 (1992).Google Scholar
10. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, J. Wiley, New York, 1978.Google Scholar
11. Sanchez, C., Alonso, B., Chapusot, F., Ribot, F. and Audebert, P., J. Sol-Gel Sci. & Techn. 2, 161 (1994).Google Scholar
12. Crans, D.C., Chen, H., Felty, R.A., J. Am. Chem. Soc. 114, 4543 (1992).Google Scholar