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Structural data of a cobalt molybdate type Φx

Published online by Cambridge University Press:  06 March 2012

Luz Amparo Palacio
Affiliation:
Department of Chemical Engineering, University of Antioquia, A. A. 1226, Medellín, Colombia
Adriana Echavarría
Affiliation:
Department of Chemical Engineering, University of Antioquia, A. A. 1226, Medellín, Colombia
Carlos Saldarriaga
Affiliation:
Department of Chemical Engineering, University of Antioquia, A. A. 1226, Medellín, Colombia

Abstract

A new cobalt molybdate with the formula NaCo2OH(H2O)(MoO4)2 was synthesized by hydrothermal reaction at 200 °C and was found to possess the Φx type structure. The crystalline system of this material is monoclinic and its cell parameters are a=9.3792 (2), b=6.3331 (1), c=7.6281 (2) Å and β=115.832°, obeying the C2/m space group symmetry.

Type
New Diffraction Data
Copyright
Copyright © Cambridge University Press 2005

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References

Kraus, W., and Nolze, G. (1999). POWDERCELL for Windows, v2.3, Federal Institute for Materials Research and Testing, Rudower Chaussee 5, 12489 Berlin, Germany.Google Scholar
Laugier, J., and Bochu, B. (2000). CHECKCELL, Laboratoire des Matériaux et du Génie Physique, Ecole Nationale Supérieure de Physique de Grenoble (INPG) Domaine Universitaire BP46, 38402 Saint Martin d’Hères.Google Scholar
Palacio, L. (2001). Doctoral thesis in Chemical Engineering, Universidad Nacional del Litoral, Santafé, Argentina, and Universidad de Antioquia, Medellín, Colombia.Google Scholar
Palacio, L., and Saldarriaga, C. (2000). “X-ray powder diffraction data for zinc molybdate, Na(OH)Zn2(MoO4)2.2.5H2O,Powder Diffr. PODIE2 15, 191192. pdj, PODIE2 CrossRefGoogle Scholar
Palacio, L., Echavarría, A., and Saldarriaga, C. (2001). “Crystal structure of a cobalt molybdate type Φx: NaCo2OH(H2O)(MoO4)2,Int. J. Inorg. Mater. IJIMCR 3, 367371. a83, IJIMCR CrossRefGoogle Scholar
Pezerat, H.(1961). “Contribution a` l’étude des molybdates hydrates de zinc, cobalt et nicke,” C. R. Acad. Sci. Paris 261, 5490–5493.Google Scholar
Roisnel, T., and Rodríguez-Carvajal, J. (1998). WINPLOTR, Laboratoire Léon Brillouin (CEA-CNR), Centre dE´tudes de Saclay, 91191 Gif-sur-Yvette, Cedes (France) and Laboratoire de Chimie du Solide et Inorganique Moléculaire (UMR6511), Université de Rennes 1, 35042 Rennex cedex (France). http://www-llb.cea.fr/fullweb/winplotr/winplotr.htm.Google Scholar
Shirley, R. (1999). The CRYSFIRE System for Automatic Powder Indexing: User’s Manual (Lattice, Surrey, England).Google Scholar
Visser, J. W. (1969). “A Fully Automatic Program for Finding the Unit Cell from Powder Data,” J. Appl. Crystallogr. JACGAR 2, 8995. acr, JACGAR Google Scholar
Werner, P.-E., Eriksson, L., and Westdahl, M. (1985). “TREOR, a Semi-Exhaustive Trial-and-Error Powder Indexing Program for All Symmetries,” J. Appl. Crystallogr. JACGAR 18, 367370. acr, JACGAR CrossRefGoogle Scholar