Hostname: page-component-76fb5796d-wq484 Total loading time: 0 Render date: 2024-04-26T01:31:48.867Z Has data issue: false hasContentIssue false

Continuous Casting of Particulate Silica Gels

Published online by Cambridge University Press:  21 February 2011

E. M. Rabinovich
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
K. A. Jackson
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
Nonna A. Kopylov
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
Get access

Abstract

A feasibility study of continuous casting of particulate silica sols has been conducted. The process consists in measured pumping of the sol and a gelling agent into a heated mold where the sol gels. The gel is continuously pushed out of the cylindrical mold by the pressure of the pumped sol. Gel rods of 2.5 cm diameter, up to 150 cm long, were prepared by this method. Temperature dependence of the gelation was studied, and activation energies of the process were determined.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Rabinovich, E. M., Johnson, D. W. Jr., MacChesney, J. B., and Vogel, E. M., ”Preparation of high-silica glass from colloidal gels: I, Preparation for sintering and properties of sintered glasses”, J. Amer. Ceram. Soc., 66 (10), pp. 683688 (1983).CrossRefGoogle Scholar
2. Johnson, D. W. Jr., Rabinovich, E. M., MacChesney, J. B., and Vogel, E. M., ”Preparation of high-silica glass from colloidal gels: II, Sintering”, J. Amer. Ceram. Soc., 66 (10) pp. 688693 (1983).CrossRefGoogle Scholar
3. MacChesney, J. B., Johnson, D. W., Fleming, D. A., and Walz, F. W., ”Hybridized sol-gel process for optical fibers”, Electronics Lett., 23 (19), pp. 10051006 (1987).Google Scholar
4. Rabinovich, E. M., ”Particulate silica gels and glasses from the sol-gel process”, pp. 260294 in Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics and Specialty Shapes”, Ed. Klein, L. C., Noyes Publ., Park Ridge, NJ (1988).Google Scholar
5. Her, R. K., The Chemistry of Silica, Wiley, NY (1979).Google Scholar
6. Rabinovich, E. M., Kopylov, N. J., ”Rheological behavior of low-surface-area particulate silica sols in the presence of F- ions”, pp. 281293, in Ultrastructure Processing of Advanced Ceramics, Mackenzie, J. D. and Ulrich, D. R., eds., Wiley, NY 1988.Google Scholar
7. Rabinovich, E. M., Kopylov, N. A., Kurkjian, C. R., and Fleming, D. A., ”Mechanical strength of particulate silica gels”, to be published.Google Scholar