Hostname: page-component-76fb5796d-wq484 Total loading time: 0 Render date: 2024-04-26T12:38:06.221Z Has data issue: false hasContentIssue false

The Evaluation of SrBi2Ta2O9 Films for Ferroelectric Memories

Published online by Cambridge University Press:  10 February 2011

C.D. Gutleben*
Affiliation:
Sony Corporation Research Center, Yokohama, Japan.
Get access

Abstract

For use in ferroelectric memories, the layer structure ferroelectric SrBi2Ta2O9 (SBT) appears to have some stability-related advantages over the more commonly known PZT class of ferroelectrics. Currently we are evaluating the feasibility of integrating this material into a state of the art CMOS memory process. Our primary scientific goal is to identify the intrinsic limitations of SBT which may restrict the engineering applications of films grown by even perfectly optimized processes. To this end we have utilized a wide variety of microanalysis probes to examine polycrystaline SBT films grown under various conditions by both MOD and Flash MOCVD. We have found that X-ray diffraction methods must be supplemented by high resolution X-ray photoelectron spectroscopy (XPS) in order to fully analyze the secondary phases which are commonly incorporated in SBT films. The more complete knowledge of film microstructure that this provides has enabled us to relate phase structure to growth and annealing conditions. XPS has also given us some insight into the initial stages of the growth chemistry of SBT on various Pt surfaces.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. A-Paz de Araujo, C., Cuchiaro, J.D., McMillan, L.D., Scott, M.C. and Scott, J.F., Nature 374, 627 (1995).Google Scholar
2. Rodriguez, Mark A., Boyle, Timothy J., Hernandez, Bernadette A., Buchheit, Catherine D., and Eatough, Mark O. in Polycrystalline Thin Films: Structure, Texture, Properties and Applications II, edited by Frost, H.J., Ross, C.A., Parker, M.A., and Holm, E.A. (Mater. Res. Soc. Proc. 403, Pittsburg, PA 1995).Google Scholar
3. Gopalakrishnan, J., Ramanan, A., Rao, C.N.R., Jefferson, D.A., and Smith, David J., J. Solid State Chem. 55, 101 (1984).Google Scholar
4. Aurivillius, B., Ark. Kemi. 1, 463 (1949).Google Scholar
5. Smolenskii, G.A., Isupov, V.A. and Agranovskaya, A.I., Sov. Phys. Solid State, 3, 651 (1961)Google Scholar
6. Subbarao, E.C., J. Phys. Chem. Solids, 23, 665 (1962).Google Scholar
7. Newnham, R.E., Wolfe, R.W., Horsey, R.S., Diaz-Colon, F.A., and Kay, M.I., Mat. Res. Bull 8, 1183 (1973); D.A. Rae, J.G. Thompson, and R.L. Withers, Acta Cryst. B 48, 428 (1992).Google Scholar
8. Amanuma, Kazushi, Hase, Takashi, and Miyasaka, Yoichi, Appl. Phys. Lett. 66, 221 (1995); Seshu B. Desu and Tingkai Li, Mat. Sci. and Eng. B34, L4 (1995)Google Scholar
9. Watanabe, Hitoshi, Mihara, Takashi, Yoshimori, Hiroyuki and Araujo, Carlos A-Paz de, Jpn. J. Appl. Phys. 34 5240 (1995).Google Scholar
10. Nanamatsu, Satoshi, Kimura, Masakazu, and Kawamura, Tsutomu, J. Phys. Soc. Jpn. 38, 817 (1975).Google Scholar
11. Tanaka, Isao, Sato, Yuzo and Kojima, Hironao, J. Crys. Growth, 99 837 (1990).Google Scholar
12. Mercurio, D., Champamaud-Mesjard, J.C., Frit, B., Conflant, P., Boivin, J.C., and Vogt, T., J. Solid State Chem. 112, 1 (1994).Google Scholar
13. Zhou, Wuzong, J. Solid State Chem. 101, 1 (1992).Google Scholar
14. Gutleben, C.D., Ikeda, Y., Isobe, C., Machida, A., Ami, T., Hironaka, K. and Morita, E., in Metal-Organic Chemical Vapor Deposition of Electronic Ceramics II, edited by Desu, Seshu B., Beach, David B., and Buskirk, P.C. Van, (Mater. Res. Soc. Proc. 415, Pittsburgh, PA 1995).Google Scholar
15. Ami, T., Hironaka, K., Isobe, C., Nagel, N., Sugiyama, M., Ikeda, Y., Watanabe, K., Machida, A., Miura, K. and Tanaka, M..Google Scholar
16. Doniach, S. and Sunjic, M., J. Phys. C 3, 285 (1970).Google Scholar