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ZnGa2O4:Mn2+ Phosphors Grown by Laser Floating Zone

Published online by Cambridge University Press:  28 September 2012

N. F. Santos
Affiliation:
Department of Physics, Laboratory I3N, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal
J. Rodrigues
Affiliation:
Department of Physics, Laboratory I3N, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal
C. Nico
Affiliation:
Department of Physics, Laboratory I3N, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal
A. J. S. Fernandes
Affiliation:
Department of Physics, Laboratory I3N, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal
F. M. Costa
Affiliation:
Department of Physics, Laboratory I3N, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal
T. Monteiro
Affiliation:
Department of Physics, Laboratory I3N, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal

Abstract

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Cubic zinc gallate (c-ZnGa2O4) has attracted the attention of the scientific community due to its potential phosphor applications, namely in field emission displays (FEDs) and other electroluminescent devices. Among other advantages, this oxide matrix shows superior thermal and chemical stability when compared to ZnS based phosphors. Most of the above mentioned works comprise nanostructures, thin films or pressed pellets while scarce information is found on bulk c-ZnGa2O4 material. In particular, no records were found regarding c-ZnGa2O4 crystal growth by the laser floating zone (LFZ) technique. In this work, crystalline fibres of manganese doped (0.01 mol %) zinc gallate were produced via LFZ in order to investigate its applicability in efficient phosphors. The transition metal ions are suitable activators and show some advantages over the widely used rare earths, namely at environmental and economic levels.

Type
Materials Sciences
Copyright
Copyright © Microscopy Society of America 2012