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Etch Selectivity of Novel Epitaxial Layers for Bulk Micromachining

Published online by Cambridge University Press:  10 February 2011

J. T. Borenstein
Affiliation:
Charles Stark Draper Laboratory, 555 Technology Square, Cambridge, MA 02139
N. D. Gerrish
Affiliation:
Charles Stark Draper Laboratory, 555 Technology Square, Cambridge, MA 02139
M. T. Currie
Affiliation:
Department of Materials Science & Engineering, MIT, 77 Massachusetts Avenue, Cambridge, MA 02139
E. A. Fitzgerald
Affiliation:
Department of Materials Science & Engineering, MIT, 77 Massachusetts Avenue, Cambridge, MA 02139
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Abstract

The present work demonstrates very high etch selectivity for a novel epitaxial layer in several standard bulk micromachining etchants. High selectivities have previously been achieved using high-concentration boron diffusions, resulting in a wide array of high performance micromechanical sensors. However, doping gradients, precipitates and dislocation arrays generated from the high boron concentrations can have deleterious effects on device performance. In this work, we report on the performance of a novel epitaxial structure composed of a silicon-germanium alloy device layer over a graded buffer layer. Chemical and microstructural analysis of the epitaxial layers reveal high purity and minimal defect densities. The selectivities of this layer and of boron-diffused layers are determined for a variety of etching conditions. High selectivity against low-doped silicon substrates is demonstrated in both ethylenediamine pyrocatechol and potassium hydroxide. Micromachined structures built using the SiGe epitaxial layer show smooth surfaces and precise build dimensions.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

1. Gianchandani, Y. and Najafi, K., “A Bulk Silicon Dissolved Wafer Process for Microelectromechanical Sensors,” Tech. Dig. IEDM, Washington DC, 1991, 2951.Google Scholar
2. Cho, S.T., “A Batch Dissolved Wafer Process for Low Cost Sensor Applications,” SPIE Vol. 2639 (1995) 10.Google Scholar
3. Weinberg, M.S., Borenstein, J.T., Connelly, J., Kourepenis, A., Ward, P. and Heiertz, J., “Applications of Draper/Boeing Micromechanical Inertial Instruments,” Sensors Expo, 1998.Google Scholar
4. Kourepenis, A., Borenstein, J., Connelly, J., Elliott, R., Ward, P. and Weinberg, M., “Performance of MEMS Inertial Sensors,” Proc. AIAA GN&C Conference, Boston, MA, 1998.Google Scholar
5. Bernstein, J.J. and Borenstein, J.T., “A Micromachined Si Condenser Microphone with On- Chip Amplifier,” Solid State Sensor and Actuator Workshop, 1996, p. 239.Google Scholar
6. Borenstein, J.T. and Preble, D.M., “Yield Enhancement in Micromechanical Sensor Fabrication using Statistical Process Control”, SPIE Vol. 3223, 1997, p. 276.Google Scholar
7. Wu, K.C., Shay, P.A., Borenstein, J.T. and Fitzgerald, E.A., “Structural Characterization of P++ Si:B Layers for Bulk Micromachining,” MRS Symp. Vol. 444 (1997) 197.Google Scholar
8. Fitzgerald, E.A., Wu, K.C., Currie, M., Gerrish, N., Bruce, D. and Borenstein, J., “Silicon-Based Epitaxial Films for MEMS,” MRS Symposium Proceedings, Spring 1998, in pressGoogle Scholar
9. Borenstein, J. T., Greiff, P., Sohn, J.B. and Weinberg, M.S., “Characterization of Membrane Curvature in Micromechanical Silicon Accelerometers and Gyroscopes Using Optical Interferometry”, SPIE Vol. 2879, 1996, 116.Google Scholar
10. Seidel, H., Csepregi, L., Heuberger, A. and Baumgärtel, H., “Anisotropic Etching of Crystalline Silicon in Alkaline Solutions: II. Influence of Dopants,” J. Electrochem. Soc., 137 (1990) 3626.Google Scholar
11. Palik, E.D., Glembocki, O.J. and Heard, I. Jr., “Study of Bias-Dependent Etching of Si in Aqueous KOH,” J. Electrochem. Soc., 134 (1987) 408.Google Scholar