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Synthesis of Phenol/Furfural Polymer Nanotubes

Published online by Cambridge University Press:  10 February 2011

Masafumi Uota ,
Daisuke Fujikawa ,
Shinji Mohri ,
Masako Kuroki ,
Katsuya Kaikake ,
Mitsunori Yada ,
Masato Machida  and
Tsuyoshi Kijima
Masafumi Uota
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
Daisuke Fujikawa
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
Shinji Mohri
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
Masako Kuroki
Affiliation:
Department of Applied Physics, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
Katsuya Kaikake
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
Mitsunori Yada
Affiliation:
Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Saga 840-8502, Japan
Masato Machida
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
Tsuyoshi Kijima
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, Miyazaki 889-2192, Japan
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Abstract

The first synthesis of phenol-furfural polymer nanotubes of 2–3nm hollow diameter is demonstrated as well as those with a hexagonal mesostructure. These nanopolymers were obtained by the templating method using a two-step reaction. At the first step, phenol and furfural were moderately reacted into cooligomers in the presence of NaOH. The resulting cooligomeric species were fully anionized and then reacted with additional phenol and alkyl trimetyl ammonium bromide at 40-80°C. The major phase for the 80°C product obtained at low concentration of surfactant was identified as nanotubular polymers of 1.9-3 nm inside and 6 nm outside diameters depending on the chain length of surfactant. In contrast, hexagonal mesostructured polymers characterized by a definite XRD peak occurred preferentially in the reaction using high surfactant-concentrations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 775: Symposium P – Self-Assembled Nanostructured Materials , 2003 , P6.20
Copyright
Copyright © Materials Research Society 2003

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