Hostname: page-component-76fb5796d-9pm4c Total loading time: 0 Render date: 2024-04-25T19:47:57.107Z Has data issue: false hasContentIssue false

Characterization of dispersion of carbon nanotubes in polymer matrices

Published online by Cambridge University Press:  07 February 2012

Laura Peña-Parás
Affiliation:
Universidad de Monterrey, Ave. Morones Prieto 4500 Pte. C. P., San Pedro Garza García, N. L. 66238, México, laura.pena@udem.edu.mx
Enrique V. Barrera
Affiliation:
Rice University, 6100 Main Street, Houston, TX 77098, USA.
Get access

Abstract

Dispersions of carbon nanotube polymer composites were characterized by Raman mapping.Single-walled nanotubes (SWNTs), double-walled nanotubes (DWNTs), multi-walled nanotubes (MWNTs), and XD-grade carbon nanotubes (XD-CNTs) were dispersed in a vinyl ester (VE) resin using an ultrasonic probe at a fixed frequency. SWNTs were functionalized with succinic acid peroxide (SAP) to enhance dispersion. Increasing ultrasonication energy was found to improve the distribution of carbon nanotubes (CNTs) and decrease the size of ropes, whereas excessive amounts of energy were found to result in damage. The quality of dispersion was verified through optical microscopy and scanning electron microscopy (SEM).

Type
Articles
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Iijima, S., Nature 354 (6348), 56-58 (1991).Google Scholar
2. Gryshchuk, O., Karger-Kocsis, J., Thomann, R., Konya, Z., and Kiricsi, I., Compos. Part A-Appl.S. 37(9), 12521259, (2006).Google Scholar
3. Salvetat, J. P., Briggs, G. A. D., Bonard, J. M., Bacsa, R. R., Kulik, A. J., Stöckli, T., Burnham, N. A., and , L. F., Phys. Rev. 82(5), 944947 (1999).Google Scholar
4. Gojny, F. H., Wichmann, M. H. G., Kopke, U., Fiedler, B., and Schulte, K., Compos. Sci.Technol 64(15), 23632371 (2004).Google Scholar
5. Seyhan, T., Gojny, F. H., Tanoglu, M., and Schulte, K., Eur. Polym. J. 43(7), 28362847 (2007).Google Scholar
6. Park, C., Ounaies, Z., Watson, K. A., Crooks, R. E., Smith, J. Jr, Lowther, S. E., Connell, J. W., Siochi, E. J., Harrison, J. S., St. Clair, T. L., Chem. Phys. Lett. 364, 303308, (2002).Google Scholar
7. Niyogi, S., Hamon, M. A., Perea, D. E., Kang, C. B., Zhao, B., Pal, S. K., Wyant, A. E., E.Itkis, M., and Haddon, R. C.., J. Phys. Chem. B 107(34), 87998804 (2003).Google Scholar
8. Hilding, J., Grulke, E. A., Zhang, Z. G., and Lockwood, F., J. Disper. Sci. Technol. 24(1), 141 (2003).Google Scholar
9. Strano, M. S., Moore, V.C., Miller, M. K., Allen, M. J., Haroz, E. H., Kittrell, C., Hauge, R. H., Smalley, R. E., J. Nanosci. Nanotechnol. 3(6), 8186 (2003).Google Scholar
10. Peng, H., Alemany, L. B., Margrave, J. L., and Khabashesku, V. N., J. Am. Chem. Soc. 125(49), 1517415182 (2003).Google Scholar
11. Zhu, J. and Peng, H., Adv. Funct. Mater. 14(7), 643648 (2004).Google Scholar
12. Zhu, J., Kim, J., Peng, H., Margrave, J. L., Khabashesku, V. N., and Barrera, E. V., Nano Lett.., 3(8), 11071113 (2003).Google Scholar
13. Lucas, , Zakri, C., Maugey, M., Pasquali, M., van der Schoot, P., and Poulin, P., J. Phys. Chem. C 113(48), 2059920605 (2009).Google Scholar
14. Dresselhaus, M. S., Dresselhaus, G., and Jorio, A., J. Phys. Chem. C 111(48), 1788717893 (2007).Google Scholar
15. Dresselhaus, M. S., Dresselhaus, G., Saito, R., and Jorio, A., Phys. Rep. 409(2), 4799 (2005).Google Scholar
16. Du, F., Scogna, R. C., Zhou, W., Brand, S., Fischer, J. E., and Winey, K. I., Macromol. 37(24), 90489055 (2004).Google Scholar
17. Costa, S., Borowiak-Palen, E., Kruszyñska, M., Bachmatiuk, A., Kalenczukl S., R J., Mater. Sci.-Poland 26(2), 433441 (2008).Google Scholar
18. O’Connell, M. J., Sivaram, S., and Doorn, S. K., Phys. Rev. B 69(23), 235415235429 (2004).Google Scholar
19. Heller, D. A., Barone, P. W., Swanson, J. P., Mayrhofer, R. M., and Strano, M. S., J. Phys. Chem. B, 108(22), 69056909 (2004).Google Scholar
20. Jeon, K., Lumata, L., Tokumoto, T., Steven, E., Brooks, J., and Alamo, R. G., Polym. 48(16), 47514764 (2007).Google Scholar
21. Lee, Y. H., presented at the 2nd Joint Workshop on Measurement Issues in Single Wall Carbon Nanotubes, NIST Gaithersburg, Md., 2005 (unpublished).Google Scholar