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Solvothermal Pathways to Transition Metal Oxides

Published online by Cambridge University Press:  15 February 2011

Alexej Michailovski  and
Greta R. Patzke
Alexej Michailovski
Affiliation:
Laboratory of Inorganic Chemistry, ETH Zürich ETH Hönggerberg, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland
Greta R. Patzke
Affiliation:
Laboratory of Inorganic Chemistry, ETH Zürich ETH Hönggerberg, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland
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Abstract

A straightforward solvothermal pathway towards anisotropic nanoscale molybdenum, vanadium and tungsten oxides has been established. They are formed quantitatively from one-step procedures within a few days or hours of autoclave treatment in the temperature range between 100 and 220 °C. The addition of straightforward ionic additives (e.g. alkali halides) leads to a versatile interplay between the formation of novel polymolybdates(VI) and the production of oxidic nanoparticles. Key solvothermal features (role of the precursor, solvothermal parameter window, influence of ionic additives) of the individual transition metal oxides are investigated with respect to the development of general synthetic guidelines and predictive concepts.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 878: Symposium Y – Solvothermal Synthesis and Processing of Materials , 2005 , Y1.2
Copyright
Copyright © Materials Research Society 2005

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