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Synthesis and Characterization of Hydrotalcites: [Zn1−xAlx(OH)2](CO3)x/2·mH2O; x=0.25−0.66

Published online by Cambridge University Press:  10 February 2011

M. A. Valenzuela ,
E. López-Salinas ,
B. Zapata  and
J. A. Montoya
M. A. Valenzuela
Affiliation:
Instituto Politécnico Nacional-ESIQIE. UPALM, 07738, México D.F., Mexico
E. López-Salinas
Affiliation:
Instituto Mexicano del Petróleo, L. Cárdenas 152, 07730 México D. F.
B. Zapata
Affiliation:
Instituto Mexicano del Petróleo, L. Cárdenas 152, 07730 México D. F.
J. A. Montoya
Affiliation:
Instituto Mexicano del Petróleo, L. Cárdenas 152, 07730 México D. F.
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Abstract

In this work a series of [Zn1−xAlx(OH)2](CO3)x/2·mH2O; x=0.25−0.66 were prepared at constant pH in order to study the effect of the thermal treatment on their crystalline srtucture. It was found that is possible to obtain pure Zn-Al hydrotalcite materials within a x = 0.25−0.50 range in comparison with Mg-Al hydrotalcites which yield pure phases in more restricted x ranges (0.25−0.33). All Zn-Al hydrotalcites lost their layered structure at temperatures above 473 K being less stable than their parental Mg-Al hydotalcite (623 K). Specific surface areas of these materials depended strongly on the Zn/Al ratio and calcination temperature, ranging from 280 to 20 m2/g. ZnO and ZnAl2O4 compounds were detected as the calcination products at temperatures higher than 873 K.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 454: Symposium S – Advanced Catalytic Materials–1996 , 1996 , 79
Copyright
Copyright © Materials Research Society 1997

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References

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