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Versatile Water-Based Transfer of Large-Area Graphene Films onto Flexible Substrates

Published online by Cambridge University Press:  12 September 2017

Maria Kim ,
Changfeng Li ,
Jannatul Susoma ,
Juha Riikonen  and
Harri Lipsanen
Maria Kim*
Affiliation:
Department of Electronics and Nanoengineering, Aalto University, PO Box 13500, FI-00076 Aalto, Finland
Changfeng Li
Affiliation:
Department of Electronics and Nanoengineering, Aalto University, PO Box 13500, FI-00076 Aalto, Finland
Jannatul Susoma
Affiliation:
Department of Electronics and Nanoengineering, Aalto University, PO Box 13500, FI-00076 Aalto, Finland
Juha Riikonen
Affiliation:
Department of Electronics and Nanoengineering, Aalto University, PO Box 13500, FI-00076 Aalto, Finland
Harri Lipsanen
Affiliation:
Department of Electronics and Nanoengineering, Aalto University, PO Box 13500, FI-00076 Aalto, Finland
*
*E-mail: maria.grigoryeva@aalto.fi
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Abstract

Next-generation electronic devices are expected to demonstrate greater utility, efficiency and durability. Meanwhile, plastics such as polyethylene terephthalate (PET), polyethylene naphthalate (PEN) and variety of poly(para-xylylene) polymers enable transformational advantages to device shape, flexibility, weight, transparency and recyclability. Exhibiting a combination of outstanding mechanical, electrical, optical, and chemical properties of graphene with the plastic substrates could propose ideal material for the future flexible electronics. Chemical vapor deposition (CVD) allows cost-effective fabrication of a high-quality large-area graphene films, however, the critical issue is clean and noninvasive transfer of the films onto a desired substrate. The water-based delamination of CVD grown graphene on Cu can be considered as a “green” transfer process utilizing only hot deionized water. We investigated a method requiring only two essential steps: coating of 6-inch monolayer CVD graphene with transparent and flexible polymer, and Cu delamination in hot water. Proposed method is inexpensive, reproducible, environmentally friendly, waste-free and suitable for large-scale, high quality graphene. The transfer process demonstrated films with enhanced charge carrier mobility, high uniformity, free of mechanical defects, and sheet resistance as low as ∼50 Ω/sq with 96.5 % transparency at 550 nm wavelength.

Keywords

chemical vapor deposition (CVD) (chemical reaction)electrical propertiesnanoscale
Type
Articles
Information
MRS Advances , Volume 2 , Issue 60: Nanomaterials , 2017 , pp. 3749 - 3754
Copyright
Copyright © Materials Research Society 2017 

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