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An Overview of All Three Stages of the International Radiocarbon Intercomparison

Published online by Cambridge University Press:  18 July 2016

E M Scott
Affiliation:
Department of Statistics, Glasgow University, Glasgow G12 8QW, Scotland
T C Aitchison
Affiliation:
Department of Statistics, Glasgow University, Glasgow G12 8QW, Scotland
D D Harkness
Affiliation:
NERC Radiocarbon Laboratory, East Kilbride, Glasgow G75 0QU, Scotland
G T Cook
Affiliation:
Scottish Universities Research and Reactor Centre, East Kilbride, Glasgow G75 0QU, Scotland
M S Baxter
Affiliation:
Scottish Universities Research and Reactor Centre, East Kilbride, Glasgow G75 0QU, Scotland
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Abstract

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The International Collaborative Study involved a wide range of sample materials and ages and, on completion, assessed each stage independently (Scott et al 1989; Aitchison et al 1990). We combine here the three stages of the study and provide an overview of the uncertainties in the dating procedure as a whole and in its component processes. Three key optimal performance indices, related to internal and external precision and to bias, have been defined to allow quantitative assessment of Internal Consistency and External Consistency (Aitchison et al 1990). We believe that these measures provide quantitative descriptions of a laboratory's reproducibility, accuracy and precision.

For the internal consistency, we have defined the Internal Error Multiplier of the quoted error and, for the external consistency of any laboratory relative to an appropriate baseline, we have defined two indices, the Systematic Bias and External Error Multiplier of the quoted error. We have evaluated the three indices over the three stages and have assessed the relative performances of gas counting, accelerator and liquid scintillation laboratories. The quoted errors describe adequately the variability in duplicate results, but there is evidence of systematic biases and underestimation of interlaboratory variability. We have considered the contribution of pretreatment, synthesis counting to the overall variability for each laboratory type. We found that, for liquid scintillation (LS) and gas counting (GC) laboratories, ca 66% of the total variation is due to counting and sample synthesis whereas, for accelerator mass spectrometry (AMS) laboratories, the major sources of variability are the sampling and pretreatment processes.

Type
Session III
Copyright
Copyright © The American Journal of Science 

References

Aitchison, TC, Scott, EM, Harkness, DD, Baxter, MS and Cook, GT 1990 Report on Stage 3 of the International Collaborative Program. Radiocarbon, this issue.Google Scholar
ISG 1982 An inter-laboratory comparison of radiocarbon measurements in tree-rings. Nature 198: 619623.Google Scholar
Scott, EM, Baxter, MS, Harkness, DD, Aitchison, TC and Cook, GT 1989 An interim progress report on Stages 1 and 2 of the International Collaborative Program. in Long, A and Kra, RS, eds, Internatl 14C conf, 13th, Proc. Radiocarbon 31(3): 414421.Google Scholar