Hostname: page-component-76fb5796d-dfsvx Total loading time: 0 Render date: 2024-04-26T10:33:14.269Z Has data issue: false hasContentIssue false
  • English
  • Français

NMR Imaging and the Electric Quadrupole Interaction in Solid Materials

Published online by Cambridge University Press:  21 February 2011

B. H. Suits
B. H. Suits*
Affiliation:
Physics Department, Michigan Technological University, Houghton, MI 49931
Get access

Abstract

Nuclei with a spin, 1 > 1/2, possess a nuclear quadrupole moment which can couple to the electric field gradients in a material. They can be static, leading to NMR frequency shifts, or dynamic, which can influence relaxation times. In either case, an NMR image can be made which is sensitized to changes in the electric quadrupole interaction to provide a sensitive measure of the macroscopic spatial dependence of the microscopic changes in the material. Several examples are presented. Special considerations need to be given in the case when the strength of the Zeeman interaction between the nucleus and the magnetic field and/or the rf field is small compared to the electric quadrupole interaction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 217: Symposium U – Advanced Tomographic Imaging Methods for the Analysis of Materials , 1990 , 67
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Watkins, G.D. and Pound, R. V., Phys. Rev. 89, 658 (1953).CrossRefGoogle Scholar
2. Das, T.P. and Hahn, E.L., Solid State Physics, Supplement 1 (Academic Press, New York, 1958), Vol.1, P. 3ff.Google Scholar
3. Abragam, A., Principles of Nuclear Magnetism (Oxford, London, 1961).Google Scholar
4. For example, see Chingas, G.C., Miller, J.B., and Garroway, A.N., J. Magn. Reson. 66, 530 (1986), and references therein.Google Scholar
5. Suits, B.H. and White, D., Solid State Commun. 50, 291 (1984).Google Scholar
6. Feiocle, F.D. and Johnson, W.R., Phys. Rev. 187, 39 (1969).Google Scholar
7. Fukushima, E. and Roeder, S.B.W., Experimental Pulse NMR, (Addison-Wesley, MA, 1969).Google Scholar
8. Harbison, G.S., Slokenbergs, A., and Barbara, T.M., J. Chem. Phys 90, 5292 (1989).Google Scholar
9. Gilman, J.J., General Electric Research Laboratory Report 59-RL-2194, 1959.Google Scholar
10. Suits, B.H. and Lutz, J.L., J. Appl. Phys. 65, 3728 (1989).Google Scholar
11. Suits, B.H. and White, D., J. Appl. Phys. 60, 3772 (1986).Google Scholar