3 results
Preparation and Characterization of Porous Palygorskite/Carbon Composites through Zinc Chloride Activation for Wastewater Treatment
- Yan Wang, Yu Zhuang, Sheng Wang, Yin Liu, Lingbing Kong, Jianjun Li, Huayong Chen
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- Journal:
- Clays and Clay Minerals / Volume 70 / Issue 3 / June 2022
- Published online by Cambridge University Press:
- 01 January 2024, pp. 450-459
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In order to develop high-performance adsorbents to remove toxic methylene blue (MB) from wastewater, palygorskite (Plg) was utilized as a template to prepare palygorskite/carbon (Plg/C) composites by using a hydrothermal reaction in the presence of glucose. The porous Plg/C composites were then activated with ZnCl2. The effects of the dose of the activator and the activation temperature on the crystal structure, micro-morphology, specific surface area, and adsorption performance of the porous Plg/C composites were studied systematically here. X-ray diffraction (XRD) and scanning electron microscopy (SEM) results indicated that the crystal structure of Plg was destroyed during the activation process and irregular porous carbon was closely attached to the residual aluminosilicate skeleton. The activation was optimized at 400°C with a ZnCl2:Plg/C impregnation ratio of 2:1. The sample had a specific surface area of 1497.88 m2/g, together with a total pore volume and micropore volume of 1.0355 and 0.5464 cm3/g, respectively. The MB adsorption capacity was 381.04 mg/g. Such inexpensive, high-performance, porous Plg/C composites could find potential applications in wastewater treatment.
Texture and composition of magnetite in the Duotoushan deposit, NW China: implications for ore genesis of Fe–Cu deposits
- Xia Hu, Huayong Chen, Xiaowen Huang, Weifeng Zhang
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- Journal:
- Mineralogical Magazine / Volume 84 / Issue 3 / June 2020
- Published online by Cambridge University Press:
- 27 April 2020, pp. 398-411
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The Duotoushan deposit is an important Fe–Cu deposit in the Aqishan–Yamansu metallogenic belt of eastern Tianshan, NW China. Magnetite occurs in two main habits which are common in many Fe–Cu deposits, i.e. platy (TD1 Mag) and granular magnetite (TD2 Mag) have been identified at Duotoushan. Platy magnetite shows two different zones (bright and dark) based on the observations by scanning electron microscopy. The bright part (TD1-L) is the main part of TD1 magnetite and lacks inclusions. The dark part (TD1-D) is very porous and has abundant tiny silicate inclusions. Granular magnetite is usually anhedral with obvious oscillatory zoning in back-scattered electron images. In general, the dark zones of magnetite are characterised by greater Si, Ca, Al and lesser Fe contents than the bright zones. In situ X-ray diffraction (XRD) analysis shows that the lattice parameter of TD1 magnetite is approximately equal to that of standard magnetite and slightly higher than that of TD2 magnetite, indicating that some cations with ionic radii smaller than those of Fe2+ or Fe3+ entered the magnetite lattice by simple or coupled substitution mechanisms in TD2 magnetite.
The results in the present study show that the effects of temperature and $f_{{\rm O}_ 2}$ on platy magnetite are very limited and the changing fluid composition might be the major controlling factor for the formation of Duotoushan platy magnetite. Although the possibility that mushketovite transformed from hematite cannot be excluded entirely, evidence from in situ XRD data, pore-volume ratio calculation and the growth habit of intergrown minerals indicates that platy magnetite (TD1) coexisting with amphibole was more likely to have been precipitated originally from hydrothermal fluid. This was then affected by changes in the fluid composition which consequently led to dissolution of primary magnetite (TD1-L) and re-precipitation of TD1-D magnetite (with abundant porosity and mineral inclusions). Meanwhile, granular magnetite (TD2) with oscillatory zoning, and coexisting with epidote and quartz, was precipitated from fluid with periodic variation in temperature. These oscillatory zones are characterised by bands enriched in Si, Al and Ca alternating with bands depleted in these elements. The present investigation revealed a complex evolutionary process for magnetite formation in the Duotoushan deposit. The importance of combined investigation of texture and compositional characterisation of magnetite for study of the ore genesis and evolution of Fe–Cu deposits is highlighted.
Triassic shoshonitic dykes from the northern North China craton: petrogenesis and geodynamic significance
- LEBING FU, JUNHAO WEI, TIMOTHY M. KUSKY, HUAYONG CHEN, JUN TAN, YANJUN LI, LINGJUN KONG, YONGJIAN JIANG
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- Journal:
- Geological Magazine / Volume 149 / Issue 1 / January 2012
- Published online by Cambridge University Press:
- 09 March 2011, pp. 39-55
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Zircon U–Pb ages, major and trace element geochemistry and Sr, Nd and Pb isotope compositions of diorite and diorite porphyry dykes from the Jinchanggouliang (JCGL) gold ore field on the northern margin of the North China craton (NCC) were studied to investigate their sources, petrogenesis and geodynamic significance. LA-ICP-MS zircon U–Pb dating reveals three major age groups of 2500 Ma (n = 2), 253 ± 7 Ma (n = 5) and 227 ± 1 Ma (n = 9). The inherited ages of 2500 Ma, contemporary with the Archaean NCC continental growth, imply that crustal material was involved in the magma source. The igneous zircons with a concordia age of 227 ± 1 Ma may record the emplacement age of the JCGL dykes. Both diorite and diorite porphyry exhibit a wide range of SiO2 and MgO contents and are characterized by high concentrations of Na2O+K2O and Al2O3, and low abundances of P2O5 and TiO2. They are enriched in large ion lithophile elements and light rare earth elements without significant Eu anomalies, and depleted in high-field-strength elements; all are categorized as shoshonitic rocks. All samples show a narrow range of Sr isotope compositions with initial 87Sr/86Sr ratios from 0.70394 to 0.70592, variable εNd(t) values (1.1 to −12.0) and TDM2 ages of 913–1972 Ma. Their Pb isotope compositions form continuous variation trends and plot in the fields between enriched mantle 1 (EM1) and lower continental crust (LCC). The above results suggest that the JCGL dykes studied could have been derived from mixing of lower crust, lithospheric mantle of the NCC and ascending asthenospheric melt in a post-orogenic extensional geodynamic setting. These shoshonitic dykes, together with the geochronological data of regional ENE-trending retrograded eclogites, ophiolites, continental arc magmatic belt, A-type granite, alkaline intrusions and metamorphic core complex from the northern NCC and Central Asian Orogenic Belt (CAOB) suggest that closure of the Palaeo-Asian Ocean (i.e. stage of pre-collision to collision) had completed during latest Permian to earliest Triassic time, and that the CAOB was subsequently tectonically dominated by post-orogenic extensional regimes. The involvement of asthenospheric melt in the magma source implies that the sub-continental lithospheric mantle (SCLM) of the NCC had been modified, and the onset of lithospheric destruction and thinning beneath the northern NCC may have occurred in Middle–Late Triassic time as a result of post-orogenic subducting slab detachment and lithospheric delamination.