2 results
Geochemical characteristics and resource potential analysis of Chang 7 organic-rich black shale in the Ordos Basin
- JIANGMIN DU, YANDE ZHAO, QINGCHUN WANG, YANQIU YU, HUI XIAO, XIANKUI XIE, YUGUO DU, ZIMIAO SU
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- Journal:
- Geological Magazine / Volume 156 / Issue 7 / July 2019
- Published online by Cambridge University Press:
- 19 December 2018, pp. 1131-1140
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The Ordos Basin is the largest and most important intracontinental sedimentary depression in China, and a significant amount of crude oil resources has developed within this Mesozoic formation. High-grade organic-rich shale is prevalent in the large-scale areas of the Chang 7 sedimentary stage and provides essential hydrocarbon resources for abundant oil enrichment in the Mesozoic. This research investigated the geochemical characteristics of Chang 7 shale using core samples and well logs and via laboratory tests. In addition, the microscopic components of the shale organic matter (OM), biological marker compounds, carbon isotopes, enrichment grade of trace elements, and elemental ratio were analysed systematically. Moreover, the aspects related to the shale OM source, sedimentary environment and resource potential were evaluated. Our results revealed that spherical alginate and calcium spherical alginate were predominant in the micropetrological components of the shale. Many biomarkers, including n-alkanes, steranes and terpanes, were detected in the gas chromatography – mass spectrometry spectra. An analysis of n-alkanes, regular sterane shapes (C21−/C22− and C26+C27/C28+C29), odd–even predominance index (OEP) and carbon preference index (CPI) values and carbon isotope distributions showed that OM was produced from aquatic organisms. The indicators of trace elements, such as Sr/Ba and V/V+Ni, combined with the biomarker compound in Pr/Ph and the gammacerane index showed the presence of a semi-deep – deep lake environment containing fresh–brackish water. In addition, the hydrocarbon conversion rate index and shale rock pyrolysis parameters revealed that Chang 7 has a high hydrocarbon generation ability and hydrocarbon expulsion efficiency.
Silica sand resources in the Netherlands
- M.J. van der Meulen, W.E. Westerhoff, A. Menkovic, S.H.L.L. Gruijters, C.W. Dubelaar, D. Maljers
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- Journal:
- Netherlands Journal of Geosciences / Volume 88 / Issue 3 / November 2009
- Published online by Cambridge University Press:
- 24 March 2014, pp. 147-160
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Silica sand, (almost) pure quartz sand, is a valuable and scarce mineral resource within the shallow Dutch subsurface. High-grade deposits are exploited in the southeasternmost part of the country, as raw material for the glass, ceramic, chemical and other process industries. Dutch land-use policy requires that scarce mineral resources (including silica sand) are taken into consideration in spatial planning and when preparing for largescale engineering or construction works. For this purpose, and in order to review the long-term possibilities for home production of silica sand, we determined resource potential nationally.
Our approach was (1) to establish the relevant conditions and processes associated with the deposition of the currently exploited sands, (2) identify lithostratigraphic units that are genetically similar or are otherwise known to contain quartz-rich sands, and (3) query the Dutch geological survey's borehole database for potential silica sand occurrences within those units. As we have to rely on non-dedicated data, the latter step was undertaken using a largely qualitative set of lithological search parameters. Finally, a limited number of available chemical analyses was used for preliminary verification purposes.
Using this approach, we identified three prospective areas: one in the north of the province of Limburg and east of the province of Noord-Brabant(~750 km2), one in the central south of Noord-Brabant (~45 km2), and one in the east of the Gelderland and Overijssel provinces (~1,200 km2). For each area, first-order characteristics of possible silica sand resources are presented (type of deposit, depth, approximate thickness). In the terms of current reporting conventions, we resolved silica sand occurrence to the level of ‘reconnaissance mineral resource’ or ‘exploration result’, and our results do not constitute a formal resource declaration. Available chemical data suggest that the resources in the first two areas could be or become economic, although the grades are lower than those of the currently exploited resources. The third area is less promising in that respect, but available data is too limited to reject the area in this stage. Even so, we tentatively conclude that home production of silica sand can probably be maintained after the reserves in Limburg are depleted.
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