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Polymorphic transformations between olivine, wadsleyite and ringwoodite: mechanisms of intracrystalline nucleation and the role of elastic strain
- Ljuba Kerschhofer, Catherine Dupas, Ming Liu, Thomas G. Sharp, William B. Durham, David C. Rubie
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- Journal:
- Mineralogical Magazine / Volume 62 / Issue 5 / October 1998
- Published online by Cambridge University Press:
- 05 July 2018, pp. 617-638
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Kinetic models and rate equations for polymorphic reconstructive phase transformations in polycrystalline aggregates are usually based on the assumptions that (a) the product phase nucleates on grain boundaries in the reactant phase and (b) growth rates of the product phase remain constant with time at fixed P-T. Recent observations of experimentally-induced transformations between (Mg,Fe)2SiO4 olivine (α) and its high pressure polymorphs, wadsleyite (β) and ringwoodite (γ), demonstrate that both these assumptions can be invalid, thus complicating the extrapolation of experimental kinetic data. Incoherent grain boundary nucleation appears to have dominated in most previous experimental studies of the α–β–γ transformations because of the use of starting materials with small (<10–20 µm) grain sizes. In contrast, when large (0.6 mm) olivine single crystals are reacted, intracrystalline nucleation of both β and γ becomes the dominant mechanism, particularly when the P-T conditions significantly overstep the equilibrium boundary. At pressures of 18–20 GPa intracrystalline nucleation involves (i) the formation of stacking faults in the olivine, (ii) coherent nucleation of γ-lamellae on these faults and (iii) nucleation of β on γ. In other experiments, intracrystalline nucleation is also observed during the β-γ transformation. In this case coherent nucleation of γ appears to occur at the intersections of dislocations with (010) stacking faults in β, which suggests that the nucleation rate is stress dependent. Reaction rims of β/γ form at the margins of the olivine single crystals by grain boundary nucleation. Measurements of growth distance as a function of time indicate that the growth rate of these rims decreases towards zero as transformation progresses. The growth rate slows because of the decrease in the magnitude of the Gibbs free energy (stored elastic strain energy) that develops as a consequence of the large volume change of transformation. On a longer time scale, growth kinetics may be controlled by viscoelastic relaxation.
Oceanic crust generation in an island arc tectonic setting, SE Anatolian orogenic belt (Turkey)
- OSMAN PARLAK, VOLKER HÖCK, HÜSEYİN KOZLU, MICHEL DELALOYE
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- Journal:
- Geological Magazine / Volume 141 / Issue 5 / September 2004
- Published online by Cambridge University Press:
- 06 October 2004, pp. 583-603
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A number of Late Cretaceous ophiolitic bodies are located between the metamorphic massifs of the southeast Anatolian orogenic system. One of them, the Göksun ophiolite (northern Kahramanmaraş), which crops out in a tectonic window bounded by the Malatya metamorphic units on both the north and south, is located in the EW-trending nappe zone of the southeast Anatolian orogenic belt between Göksun and Afşin (northern Kahramanmaraş). It consists of ultramafic–mafic cumulates, isotropic gabbro, a sheeted dyke complex, plagiogranite, volcanic rocks and associated volcanosedimentary units. The ophiolitic rocks and the tectonically overlying Malatya–Keban metamorphic units were intruded by syn-collisional granitoids (∼ 85 Ma). The volcanic units are characterized by a wide spectrum of rocks ranging in composition from basalt to rhyolite. The sheeted dykes consist of diabase and microdiorite, whereas the isotropic gabbros consist of gabbro, diorite and quartzdiorite. The magmatic rocks in the Göksun ophiolite are part of a co-magmatic differentiated series of subalkaline tholeiites. Selective enrichment of some LIL elements (Rb, Ba, K, Sr and Th) and depletion of the HFS elements (Nb, Ta, Ti, Zr) relative to N-MORB are the main features of the upper crustal rocks. The presence of negative anomalies for Ta, Nb, Ti, the ratios of selected trace elements (Nb/Th, Th/Yb, Ta/Yb) and normalized REE patterns all are indicative of a subduction-related environment. All the geochemical evidence both from the volcanic rocks and the deeper levels (sheeted dykes and isotropic gabbro) show that the Göksun ophiolite formed during the mature stage of a suprasubduction zone (SSZ) tectonic setting in the southern branch of the Neotethyan ocean between the Malatya–Keban platform to the north and the Arabian platform to the south during Late Cretaceous times. Geological, geochronological and petrological data on the Göksun ophiolite and the Baskil magmatic arc suggest that there were two subduction zones, the first one dipping beneath the Malatya–Keban platform, generating the Baskil magmatic arc and the second one further south within the ocean basin, generating the Göksun ophiolite in a suprasubduction zone environment.