Hostname: page-component-76fb5796d-zzh7m Total loading time: 0 Render date: 2024-04-26T05:33:19.279Z Has data issue: false hasContentIssue false
  • English
  • Français

Challenges and Solutions for Handling and Characterizing Alkali-Tc-Oxide Salts

Published online by Cambridge University Press:  08 February 2018

Jamie L. Weaver ,
Chuck Soderquist ,
Nancy Washton ,
Paul Gassman ,
Eric Walter ,
Mark Bowden ,
Wayne Lukens  and
John S. McCloy
Jamie L. Weaver
Affiliation:
Department of Chemistry, Washington State University, Pullman, WA99164, USA Pacific Northwest National Laboratory, Richland, WA99352, USA
Chuck Soderquist
Affiliation:
Pacific Northwest National Laboratory, Richland, WA99352, USA
Nancy Washton
Affiliation:
Pacific Northwest National Laboratory, Richland, WA99352, USA
Paul Gassman
Affiliation:
Pacific Northwest National Laboratory, Richland, WA99352, USA
Eric Walter
Affiliation:
Pacific Northwest National Laboratory, Richland, WA99352, USA
Mark Bowden
Affiliation:
Pacific Northwest National Laboratory, Richland, WA99352, USA
Wayne Lukens
Affiliation:
Lawrence Berkeley National Laboratory, Berkeley, CA94720, USA
John S. McCloy*
Affiliation:
Department of Chemistry, Washington State University, Pullman, WA99164, USA Pacific Northwest National Laboratory, Richland, WA99352, USA Materials Science and Engineering Program and School of Mechanical & Materials Engineering, Washington State University, Pullman, WA99164, USA
*
*(Email: john.mccloy@wsu.edu)
Get access

Abstract

Though not often discussed explicitly in literature, sample handling and preparation for advanced characterization techniques is a significant challenge for radiological materials. In this contribution, a detailed description is given of method development associated with characterization of highly radioactive and, in some cases, hygroscopic oxides of technetium. Details are given on developed protocols, fixtures, and tooling designed for x-ray and neutron diffraction, x-ray absorption, Raman spectroscopy, magic angle spinning nuclear magnetic resonance, and electron paramagnetic resonance. In some cases, multiple iterations of improved sample holder design are described. Lessons learned in handling Tc compounds for these and similar characterization methods are discussed.

Keywords

nuclear materialsnuclear magnetic resonance (NMR)Raman spectroscopyextended x-ray absorption fine structure (EXAFS)neutron scattering
Type
Articles
Information
MRS Advances , Volume 3 , Issue 21: Scientific Basis for Nuclear Waste Management XLI , 2018 , pp. 1191 - 1200
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Segre, E. and Seaborg, G., Phys. Rev. 54, 772 (1938).Google Scholar
Deutsch, E., Libson, K., Jurisson, S. and Lindoy, L.F., In Progress in Inorganic Chemistry, edited by Lippard, S. J., (John Wiley & Sons, Inc., 1983), pp. 75.Google Scholar
Schwochau, K., Technetium: Chemistry and Radiopharmaceutical Applications, (Wiley, 2000).CrossRefGoogle Scholar
Spitsin, V.I., Rosenfeld, I.L., Persiantseva, V.P., Zamoshnikova, N.N. and Kuzina, A.F., Corrosion 21, 211 (1965).Google Scholar
Ishida, T. and Mazaki, H., Phys. Rev. B 20, 131 (1979).CrossRefGoogle Scholar
Little-Marenin, I.R. and Little, S.J., Astronom. J. 84, 1374 (1979).Google Scholar
Goriely, S., In Capture Gamma-Ray Spectroscopy and Related Topics, edited, (World Scientific, 2013), pp. 326.Google Scholar
Kemmitt, R.D.W. and Peacock, R.D., The chemistry of manganese, technetium, and rhenium: Pergamon texts in inorganic chemistry, (Pergamon Press, 1973).Google Scholar
Stennett, M.C., Lee, T.-H., Bailey, D.J., Johnstone, E.V., Heo, J. and Hyatt, N.C., MRS Adv. 2, 753 (2017).Google Scholar
Kim, D. and Kruger, A.A., J. Non-Cryst. Solids in press, (2017).Google Scholar
Soderquist, C.Z., Buck, E.C., McCloy, J.S., Schweiger, M.J. and Kruger, A.A., J. Am. Ceram. Soc. 99, 3924 (2016).Google Scholar
Neeway, J.J., Qafoku, N.P., Williams, B.D., Snyder, M.M.V., Brown, C.F. and Pierce, E.M., Appl. Geochem. 66, 210 (2016).Google Scholar
Lukens, W.W., Magnani, N., Tyliszczak, T., Pearce, C.I. and Shuh, D.K., Environ. Sci. Technol. 50, 13160 (2016).Google Scholar
Childs, B.C., Braband, H., Lawler, K., Mast, D.S., Bigler, L., Stalder, U., Forster, P.M., Czerwinski, K.R., Alberto, R., Sattelberger, A.P. and Poineau, F., Inorg. Chem. 55, 10445 (2016).Google Scholar
Banerjee, D., Kim, D., Schweiger, M.J., Kruger, A.A. and Thallapally, P.K., Chem. Soc. Rev. 45, 2724 (2016).Google Scholar
Pegg, I., Radioanal, J.. Nucl. Chem. 305, 1 (2015).Google Scholar
Luksic, S.A., Riley, B.J., Schweiger, M. and Hrma, P., J. Nucl. Mater. 466, 526 (2015).Google Scholar
Weaver, J., Soderquist, C.Z., Washton, N.M., Lipton, A.S., Gassman, P.L., Lukens, W.W., Kruger, A.A., Wall, N.A. and McCloy, J.S., Inorg. Chem. 56, 2533 (2017).CrossRefGoogle Scholar
Weaver, J., Soderquist, C., Gassman, P., Walter, E., Lukens, W. and McCloy, J.S., MRS Adv. 2, 525 (2017).Google Scholar
Lee, M.-S., Um, W., Wang, G., Kruger, A.A., Lukens, W.W., Rousseau, R. and Glezakou, V.-A., Nat. Commun. 7, 12067 (2016).CrossRefGoogle Scholar
Asmussen, R.M., Neeway, J.J., Lawter, A.R., Levitskaia, T.G., Lukens, W.W. and Qafoku, N.P., J. Nucl. Mater. 480, 393 (2016).Google Scholar
Dickson, J.O., Harsh, J.B., Lukens, W.W. and Pierce, E.M., Chem. Geol. 395, 138 (2015).Google Scholar
Soderquist, C.Z., Schweiger, M.J., Kim, D.-S., Lukens, W.W. and McCloy, J.S., J. Nucl. Mater. 449, 173 (2014).CrossRefGoogle Scholar
Buechele, A.C., McKeown, D.A., Lukens, W.W., Shuh, D.K. and Pegg, I.L., J. Nucl. Mater. 429, 159 (2012).CrossRefGoogle Scholar
Nuclear Industry Workforce Getting Younger, Nuclear Energy Institute, www.nei.org (2015).Google Scholar
Squires, L.N., Mariani, R.D., Hartmann, T. and Kennedy, J.R., Adv. X-ray Anal. 56, 54 (2012).Google Scholar
Gassman, P.L., McCloy, J.S., Soderquist, C.Z. and Schweiger, M.J., J. Raman Spectros. 45, 139 (2014).Google Scholar