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Concise Synthesis of Complex Taxane Diterpene Canataxpropellane by Photochemical Dearomatization

05 August 2019, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Our work describes the first total synthesis of a complex taxane canataxpropellane. The synthesis is based on a photechemicalr eaction - a orthodoxy-alkene-arene-photocycloaddion. The route is concise providing material for biological testing

Keywords

taxane diterpenes
Total synthesis
complex taxane
photochemistry
dipropellane

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Now Published

Total synthesis of the complex taxane diterpene canataxpropellane [opens in a new tab]
Fabian Schneider, Konstantin Samarin, Simone Zanella, Tanja Gaich journal article
Science , Volume 367, Issue 6478
Print publication date: Feb 07, 2020

Version History

Aug 05, 2019 Version 1

Version Notes

the missing co-authors were added

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.9229217.v1
D O I: 10.26434/chemrxiv.9229217.v1 [opens in a new tab]

Funding

LGFG stipend

Author’s competing interest statement

no conflict of interest

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