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Cr(II) and Cr(I) PCP Pincer Complexes: Synthesis, Structure, and Catalytic Reactivity

07 November 2019, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

We report the synthesis of the square-planar Cr(II) PCP complex [Cr(POCOP-tBu)(Br)] which is a valuable precursor for novel chromium borohydride PCP pincer complexes in formal oxidation states +I and +II.

Keywords

Chromium
PCP pincer ligand
nitrosyl complexes

Supplementary materials

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Now Published

Cr(II) and Cr(I) PCP Pincer Complexes: Synthesis, Structure, and Catalytic Reactivity [opens in a new tab]
Daniel Himmelbauer, Berthold Stöger, Luis F. Veiros, Marc Pignitter, Karl Kirchner journal article
Organometallics , Volume 38, Issue 24
Online publication date: Dec 04, 2019

Version History

Nov 07, 2019 Version 1

Version Notes

Version 1.0

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.10116692.v1
D O I: 10.26434/chemrxiv.10116692.v1 [opens in a new tab]

Funding

Austrian Science Fund P29584-N28

Author’s competing interest statement

There are is no conflict of interest

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