How to Submit
Browse
Events
Communities
About

Synthesis of Vitisin A & D: Thermal Isomerization Enabled by a Persistent Radical Equilibrium

22 November 2019, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

The total synthesis of oligomer natural products derived from resveratrol has been achieved through a putative biogenetic bond migration from a presumed common intermediate in a divergent biosynthetic pathway.

Keywords

resveratrol
persistent radical
total synthesis

Supplementary materials

Title
Description
Actions
Title
Stephenson manuscript
Description
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting and Discussion Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

Synthesis of Vitisins A and D Enabled by a Persistent Radical Equilibrium [opens in a new tab]
Kevin J. Romero, Mitchell H. Keylor, Markus Griesser, Xu Zhu, Ethan J. Strobel, Derek A. Pratt, Corey R. J. Stephenson journal article
Journal of the American Chemical Society , Volume 142, Issue 14
Online publication date: Mar 11, 2020

Version History

Nov 22, 2019 Version 1

Metrics

4,381
888
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.10294826.v1
D O I: 10.26434/chemrxiv.10294826.v1 [opens in a new tab]

Funding

National Institute of General Medical Sciences
R01GM121656
Enabling Elucidation of the Biological Activity of Resveratrol Natural Products with Synthesis
https://app.dimensions.ai/details/grant/grant.6617135 [opens in a new tab]

Author’s competing interest statement

No conflict of interest

Share