Insensitivity of Magnetic Coupling to Ligand Substitution in a Series of Tetraoxolene Radical-Bridged Fe2 Complexes

The elucidation of magnetostructural correlations between bridging ligand substitution and strength of magnetic coupling is essential to the development of high-temperature molecule-based magnetic materials. Toward this end, we report the series of tetraoxolene-bridged Fe^II₂ complexes [(Me₃TPyA)₂Fe₂(^RL)]ⁿ⁺ (Me₃TPyA = tris(6-methyl-2-pyridylmethyl)amine; n = 2: ^OMeLH₂ = 3,6-dimethoxy-2,5-dihydroxo-1,4-benzoquinone, ^ClLH₂ = 3,6-dichloro-2,5-dihydroxo-1,4-benzoquinone, Na₂[^NO2L] = sodium 3,6-dinitro-2,5-dihydroxo-1,4-benzoquinone; n = 0: ^SMe2L = 3,6-bis(dimethylsulfonium)-2,5-dihydroxo-1,4-benzoquinone diylide) and their one-electron-reduced analogues. Variable-temperature dc magnetic susceptibility data reveal the presence of weak ferromagnetic superexchange between Fe^II centers in the oxidized species, with exchange constants of J = +1.2(2) (R = OMe, Cl) and +0.3(1) (R = NO₂, SMe₂) cm⁻¹. In contrast, X-ray diffraction, cyclic voltammetry, and Mössbauer spectroscopy establish a ligand-centered radical in the reduced complexes. Magnetic measurements for the radical-bridged species reveal the presence of strong antiferromagnetic metal–radical coupling, with J = −57(10), −60(5), −58(6), and −65(8) cm⁻¹ for R = OMe, Cl, NO₂, and SMe₂, respectively. The minimal effects of substituents in the 3- and 6-positions of ^RL^x−• on the magnetic coupling strength is understood through electronic structure calculations, which show negligible spin density on the substituents and associated C atoms of the ring. Finally, the radical-bridged complexes are single-molecule magnets, with relaxation barriers of U_eff = 50(1), 41(1), 38(1), and 33(1) cm⁻¹ for R = OMe, Cl, NO₂, and SMe₂, respectively. Taken together, these results provide the first examination of how bridging ligand substitution influences magnetic coupling in semiquinoid-bridged compounds, and they establish design criteria for the synthesis of semiquinoid-based molecules and materials.