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Electrocatalytic C–N Coupling via Anodically Generated Hypervalent Iodine Intermediates

30 December 2019, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Development of new electrosynthetic chemistry promises to impact the efficiency and sustainability of organic synthesis. Here we demonstrate that anodically generated hypervalent iodine intermediates effectively couple interfacial electron transfer with oxidative C-H/N-H coupling chemistry.

Keywords

Hypervalent Iodine
Electrocatalysis Paradigm
C-H Functionalization

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Now Published

Electrocatalytic C–N Coupling via Anodically Generated Hypervalent Iodine Intermediates [opens in a new tab]
Asim Maity, Brandon L. Frey, Nathanael D. Hoskinson, David C. Powers journal article
Journal of the American Chemical Society , Volume 142, Issue 11
Online publication date: Mar 04, 2020

Version History

Dec 30, 2019 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.11472549.v1
D O I: 10.26434/chemrxiv.11472549.v1 [opens in a new tab]

Funding

Welch Foundation A-1907
National Science Foundation 1848135

Author’s competing interest statement

No conflict

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