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D4h Local Symmetric dysprosium(III) Single-Molecule Magnet with Energy Barrier Exceeding 2000 K

24 July 2020, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Three six-coordinate Dy(III) single-molecule magnets (SMMs) [Dy(OtBu)2(L)4]+ with D4h local symmetry are obtained by optimising the equatorial ligands. Compound 1 where L = 4-phenylpyridine shows an energy barrier (Ueff) of 2075(11) K, which is the third largest Ueff, and the first Ueff > 2000 K for SMMs with axial-type symmetry so far.

Keywords

Dysprosium
Six-coordinate
D4h symmetry
Single-Molecule Magnets
Energy barrier

Supplementary materials

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Now Published

A Local D 4h Symmetric Dysprosium(III) Single‐Molecule Magnet with an Energy Barrier Exceeding 2000 K** [opens in a new tab]
Xia‐Li Ding, Yuan‐Qi Zhai, Tian Han, Wei‐Peng Chen, You‐Song Ding, Yan‐Zhen Zheng journal article
Chemistry – A European Journal , Volume 27, Issue 8
Online publication date: Jan 14, 2021

Version History

Jul 24, 2020 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12696578.v1
D O I: 10.26434/chemrxiv.12696578.v1 [opens in a new tab]

Author’s competing interest statement

The authors declare that they have no conflict of interest.

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