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Nitrene Photochemistry of Manganese N-Haloamides

23 June 2021, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Here we report the synthesis and nitrene transfer photochemistry of Mn(III) N-haloamide complexes. Photolysis results in both C–H bond amination and olefinic aziridination products. Low-temperature spectroscopy indicates halogen-dependent photoreactivity: Photolysis of N-chloroamides cleaves the Mn–N bond to generate Mn(II) and amidyl radical species; in contrast, photolysis of N-iodoamides proceeds via N–I cleavage yielding a formally Mn(IV) nitrenoid.

Keywords

Metal Nitrene
Photochemistry
C-H Amination
Reactive Intermediates

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Now Published

Nitrene Photochemistry of Manganese N ‐Haloamides** [opens in a new tab]
Gerard P. Van Trieste, Kaleb A. Reid, Madeline H. Hicks, Anuvab Das, Matthew T. Figgins, Nattamai Bhuvanesh, Andrew Ozarowski, Joshua Telser, David C. Powers journal article
Angewandte Chemie International Edition , Volume 60, Issue 51
Online publication date: Nov 16, 2021

Version History

Jun 23, 2021 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-plww9
D O I: 10.26434/chemrxiv-2021-plww9 [opens in a new tab]

Funding

U.S. Department of Energy
DE-SC0018977
Welch Foundation
A-1907
Alfred P. Sloan Foundation

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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