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A monoanionic pentadentate ligand platform for scandium-pnictogen multiple bonds

30 June 2021, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

A new monoanionic pentadentate ligand is designed to accommodate Sc=E bonds (E = N, P). The imido complex is stable enough to isolate and characterize, and reacts rapidly with CO2. The phosphinidene, on the other hand, is highly reactive and induces C-C bond cleavage to yield a phosphido-pyridyl complex which also undergoes rapid reacton with CO2.

Keywords

scandium
multiple bonding
pentadentate ligand
terminal imido
phosphinidene

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Now Published

A monoanionic pentadentate ligand platform for scandium–pnictogen multiple bonds [opens in a new tab]
Evan A. Patrick, Yan Yang, Warren E. Piers, Laurent Maron, Benjamin S. Gelfand journal article
Chemical Communications , Volume 57, Issue 69
Online publication date: 2021

Version History

Jun 30, 2021 Version 1

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-mwk57
D O I: 10.26434/chemrxiv-2021-mwk57 [opens in a new tab]

Funding

Canada Research Chairs
Natural Sciences and Engineering Research Council of Canada
Alberta Innovates - Technology Futures

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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