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Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines

20 October 2021, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

We report the use of a cyclic carbodiphosphorane catalyst for ketone and imine hydroboration reactions. To our knowledge, this represents the first use of a carbodiphosphorane as an organocatalyst. The carbodiphospohorane shows superior catalytic activity compared to other neutral carbon nucleophiles tested.

Keywords

Lewis base catalysis
hydroboration
main group chemistry

Supplementary materials

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Title
Supporting Information for "Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines"
Description
Contains synthetic procedures, NMR data, and NMR spectra
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Now Published

Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines [opens in a new tab]
Cara R. Aversa-Fleener, Daniel K. Chang, Allegra L. Liberman-Martin journal article
Organometallics , Volume 40, Issue 24
Online publication date: Dec 16, 2021

Version History

Oct 20, 2021 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-zfvc9
D O I: 10.26434/chemrxiv-2021-zfvc9 [opens in a new tab]

Funding

American Chemical Society Petroleum Research Fund
62239-UNI1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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