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An [FeIII30] molecular metal oxide

26 October 2021, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Dissolution of FeBr3 in a mixture of acetonitrile and 3,4-lutidine in the presence of an amine results in the formation of an [Fe30] molecular metal oxide containing alternating layers of tetrahedral and octahedral FeIII ions. Mass spectrometry suggests the cluster is formed quickly and remains stable in solution, while magnetic measurements and DFT calculations reveal competing antiferromagnetic exchange interactions.

Keywords

Fe(III)
molecular metal oxide
magnetism
DFT
mass spectrometry

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Now Published

An [FeIII30] molecular metal oxide [opens in a new tab]
Alice E. Dearle, Daniel J. Cutler, Marco Coletta, Edward Lee, Sourav Dey, Sergio Sanz, Hector W. L. Fraser, Gary S. Nichol, Gopalan Rajaraman, Jürgen Schnack, Leroy Cronin, Euan K. Brechin journal article
Chemical Communications , Volume 58, Issue 1
Online publication date: 2022

Version History

Oct 26, 2021 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-4l0cv
D O I: 10.26434/chemrxiv-2021-4l0cv [opens in a new tab]

Funding

EPSRC
EP/P025986/1 & EP/N01331X/1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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