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Deep eutectic solvents comprising creatine and citric acid and their hydrated mixtures

25 January 2022, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

We report the phase diagram for the binary creatine–citric acid mixture which features a stable and broad eutectic region. Combinations containing 10–60 mol% creatine yield a deep eutectic solvent with a glass transition temperature at 270 K. Addition of up to 70 mol% water to the binary mixture affords retention of the eutectic nature and a handle to vary solvent viscosity and polarity.

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Now Published

Deep eutectic solvents comprising creatine and citric acid and their hydrated mixtures [opens in a new tab]
Matthew P. Heaney, Laxmi Adhikari, Asher L. Siegel, Kyle B Pekar, Jonathan B Lefton, Claire McGuire, Pokpong Rungthanaphatsophon, Justin R. Walensky, Gary A. Baker, Tomče Runčevski journal article
Chemical Communications , Volume 58, Issue 17
Online publication date: 2022

Version History

Jan 25, 2022 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-gb47v
D O I: 10.26434/chemrxiv-2022-gb47v [opens in a new tab]

Funding

Welch Foundation
N-2012-20190330
American Chemical Society Petroleum Research Fund

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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