Abstract
A systematic investigation of ethynyl N-heterocycle-substituted-λ3-iodanes (ENHIs) is presented. In a straightforward one-pot synthesis these novel reagents can be obtained in high yields bearing a variety of N-heterocycles. Their reactivity as electrophilic alkyne group transfer reagents was benchmarked in well-established as well as novel inter- and intramolecular group transfer reactions and compared to literature-known ethynyl benziodoxolones.
Supplementary materials
Title
Stabilization of Ethynyl-Substituted Aryl-λ3-Iodanes by Tethered N-Heterocylces
Description
This article describes novel EBX-derived N-heterocycle-stabilized alkynyl-iodonium salts and -iodanes.
Actions



![Author ORCID: We display the ORCID iD icon alongside authors names on our website to acknowledge that the ORCiD has been authenticated when entered by the user. To view the users ORCiD record click the icon. [opens in a new tab]](https://www.cambridge.org/engage/assets/public/coe/logo/orcid.png)