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Nonaromatic benzocorroles

10 March 2023, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Introduced here are new hybrid benzocorrole ligands, displaying both the cavity size of corroles and the dianionic character of porphyrins. Nonaromatic and yet sporting deceptively porphyrin-like optical spectra, they are readily accessible via a simple three-step synthetic protocol.

Keywords

benzocorroles
nonaromaticity
DFT calculations

Supplementary materials

Title
Description
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Title
Supporting Information for Nonaromatic benzocorroles
Description
1. General information. 2. Synthesis. 3. Crystallographic data. 4. Experimental methods. 5. Spectroscopic data. 6. Computational results. 7. Electrochemical data. 8. NMR Spectra. 9. Cartesian coordinates.
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Now Published

Nonaromatic naphthocorroles [opens in a new tab]
Łukasz Kielesiński, Francesco F. Summa, Jeanet Conradie, Hilah C. Honig, Ariel Friedman, Gugliemo Monaco, Lior Elbaz, Abhik Ghosh, Daniel T. Gryko journal article
Chemical Communications , Volume 59, Issue 36
Online publication date: 2023

Version History

Mar 10, 2023 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-qsh4c
D O I: 10.26434/chemrxiv-2023-qsh4c [opens in a new tab]

Funding

Polish National Science Center, Poland
HARMONIA 2018/30/M/ST5/00460
Research Council of Norway (AG)
324139
South African National Research Foundation (JC)
129270 and 132504

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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