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Abstract
The approach of multivariate MOFs was used to fine-tune the mechanical properties of the flexible framework DUT-49. In situ XRD, NMR and physisorption studies showed that the partial incorporation of a more rigid linker into DUT-49 framework enables a stabilization of the metastable open pore phase which led to a twofold amplification of ΔnNGA.
Supplementary materials
Title
Amplification of Negative Gas Adsorption in a multivariate framework
Description
Detailed descritprion of materials, methods and instrumentation, NMR spectra, SEM images and Pawley refinement.
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