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Modified Pickering Catalysis: Green Transfer Hydrogenation of the Tri-substituted Olefin of Tetrahydocannabinol

21 August 2024, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Green transfer hydrogenation of the trisubstituted olefin within the tetrahydrocannabinol scaffold, has been performed using minimal amount of organic solvent in water, on the basis of a modified Pickering catalysis, with greater selectivity over standard industrial conditions with decreased reaction times under ambient conditions. Examples of various solvents, surfactants, and observation of europium in the selectivity of the hydrogenated products are given.

Keywords

Green Chemistry
Hydrogenation
Catalysis
Cannabinoids
Pickering Catalysis

Supplementary materials

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Supplementary information containing reaction conditions and spectroscopy
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Version History

Aug 21, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-gbt7j
D O I: 10.26434/chemrxiv-2024-gbt7j [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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