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Energy transfer mediated alkoxy radical generation: the construction of 1,6-linkage using bifunctional oxime esters

25 September 2024, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

The generation of long-chain alkoxy radicals via visible light-induced energy transfer (EnT) has been accomplished through the design of a new class of bifunctional oxime esters derived from iminophenylacetic acid. The 1,5-hydrogen atom abstraction (HAT) of the alkoxy radicals, followed by alkylamination of alkenes, enables the construction of a 1,6-linkage across a double bond to achieve the valuable 1,6-amino alcohols.

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Version History

Sep 25, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-d8ckr
D O I: 10.26434/chemrxiv-2024-d8ckr [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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