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Electrifying P(V): Access to Polar and Radical Reactivity

04 November 2024, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Electrochemical, fully stereoselective P(V)-radical hydrophosphorylation of olefins and carbonyl compounds using a P(V) reagent is disclosed. By strategically selecting the anode material, radical reactivity is accessible for alkene hy-drophosphorylation whereas a polar pathway operates for ketone hydrophosphorylation. The mechanistic intricacies of these chemoselective transformations was explored in-depth

Keywords

Thiophosphate
Electrochemistry
Radical Reaction
Abramov
P(V)
PSI

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Version History

Nov 04, 2024 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-m5v9g
D O I: 10.26434/chemrxiv-2024-m5v9g [opens in a new tab]

Funding

NSF
CHE-2002158

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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