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Elastic frustration affecting multi-step spin crossover behaviour in two differently interpenetrated FeII-dicyanoargentate 3D Hofmann coordination polymers

25 November 2024, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

The effect of elastic frustration on the multi-step SCO behaviour has been investigated in two differently interpenetrated [Fe(DPyN){Ag(CN)2}2] Hofmann coordination polymers (CPs) (DPyN = 2,6-di(pyridin-4-yl)naphthalene), influenced by argentophilic, ionic and non-covalent interactions.

Keywords

Spin crossover
elastic frustration

Supplementary materials

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Supplementary Information contains experimental procedures, materials and methods along with crystallographic tables and other physical measurements.
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Version History

Nov 25, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-z1kkd
D O I: 10.26434/chemrxiv-2024-z1kkd [opens in a new tab]

Funding

Science and Engineering Research Board
CRG/2022/001676

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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