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Photolysis of bis(catecholato)silicates

16 December 2024, Version 2
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

We investigated chemical consequences of direct irradiation of alkyl bis(catecholato)silicates. We provide evidence for alkyl radical formation through EPR spin-trapping experiments, relative kinetics of radical formation, as well as direct observation of nitro group stabilized semiquinone radical.

Supplementary materials

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Supporting Information
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Supporting information containing spectroscopic characterization of compounds and details about EPR experiments.
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Supplementary weblinks

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GitHub repository
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Assigned NMR data, code for figures, computational models.
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Version History

Dec 16, 2024 Version 2

Version Notes

Author affiliation added

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-t0x4t-v2
D O I: 10.26434/chemrxiv-2024-t0x4t-v2 [opens in a new tab]

Funding

National Institutes of Health
P20GM113117
National Science Foundation
CHE200120
NIH Shared Instrumentation
S10RR024664, S10RR019398
NSF Chemical Instrumentation Grant
0946883

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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